PMID- 23650112
OWN - NLM
STAT- MEDLINE
DCOM- 20140328
LR  - 20130614
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 19
IP  - 26
DP  - 2013 Jun 24
TI  - Thiol-yne click reactions on alkynyl-dopamine-modified reduced graphene oxide.
PG  - 8673-8
LID - 10.1002/chem.201300225 [doi]
AB  - The large-scale preparation of graphene is of great importance due to its 
      potential applications in various fields. We report herein a simple method for 
      the simultaneous exfoliation and reduction of graphene oxide (GO) to reduced GO 
      (rGO) by using alkynyl-terminated dopamine as the reducing agent. The reaction 
      was performed under mild conditions to yield rGO functionalized with the dopamine 
      derivative. The chemical reactivity of the alkynyl function was demonstrated by 
      post-functionalization with two thiolated precursors, namely 
      6-(ferrocenyl)hexanethiol and 1H,1H,2H,2H-perfluorodecanethiol. X-ray 
      photoelectron spectroscopy, UV/Vis spectrophotometry, Raman spectroscopy, 
      conductivity measurements, and cyclic voltammetry were used to characterize the 
      resulting surfaces.
CI  - Copyright (c) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Kaminska, Izabela
AU  - Kaminska I
AD  - Institut de Recherche Interdisciplinaire (IRI), CNRS USR 3078, Universite Lille 
      1, Parc de la Haute Borne, 50 avenue de Halley, BP 70478, 59658 Villeneuve 
      d'Ascq, France.
FAU - Qi, Wang
AU  - Qi W
FAU - Barras, Alexandre
AU  - Barras A
FAU - Sobczak, Janusz
AU  - Sobczak J
FAU - Niedziolka-Jonsson, Joanna
AU  - Niedziolka-Jonsson J
FAU - Woisel, Patrice
AU  - Woisel P
FAU - Lyskawa, Joel
AU  - Lyskawa J
FAU - Laure, William
AU  - Laure W
FAU - Opallo, Marcin
AU  - Opallo M
FAU - Li, Musen
AU  - Li M
FAU - Boukherroub, Rabah
AU  - Boukherroub R
FAU - Szunerits, Sabine
AU  - Szunerits S
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130506
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
RN  - 0 (Alkynes)
RN  - 0 (Oxides)
RN  - 0 (Sulfhydryl Compounds)
RN  - 7782-42-5 (Graphite)
RN  - VTD58H1Z2X (Dopamine)
SB  - IM
MH  - Alkynes/*chemistry
MH  - Click Chemistry
MH  - Dopamine/*chemistry
MH  - Graphite/*chemistry
MH  - Nanocomposites/chemistry
MH  - Oxidation-Reduction
MH  - Oxides/chemistry
MH  - Sonication
MH  - Sulfhydryl Compounds/*chemistry
MH  - Temperature
EDAT- 2013/05/08 06:00
MHDA- 2014/03/29 06:00
CRDT- 2013/05/08 06:00
PHST- 2013/01/21 00:00 [received]
PHST- 2013/03/25 00:00 [revised]
PHST- 2013/05/08 06:00 [entrez]
PHST- 2013/05/08 06:00 [pubmed]
PHST- 2014/03/29 06:00 [medline]
AID - 10.1002/chem.201300225 [doi]
PST - ppublish
SO  - Chemistry. 2013 Jun 24;19(26):8673-8. doi: 10.1002/chem.201300225. Epub 2013 May 
      6.