PMID- 23667985
OWN - NLM
STAT- MEDLINE
DCOM- 20141219
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 31
IP  - 1
DP  - 2013 Jan
TI  - [Determination of four kinds of illegal additive residues in sprouts and source 
      beans by high performance liquid chromatography-tandem mass spectrometry].
PG  - 22-6
AB  - A reversed-phase high performance liquid chromatography coupled with tandem mass 
      spectrometric (LC-MS/MS) method was developed for the determination of 
      4-chlorophenoxyacetic acid, 6-benzylaminopurine, enrofloxacin and norfloxacin 
      residues in sprouts and source beans. The sample was extracted by acetonitrile 
      containing 0.1% acetic acid and concentrated. The chromatographic analysis was 
      carried out on a C18 column with methanol and 0.1% formic acid solution as the 
      mobile phases in gradient elution program. The MS analysis was set in 
      electrospray ionization mode and separated to two segments of positive and 
      negative modes. The precursor ions were m/z 189.9, 226.1, 359.9 and 320.1, while 
      the product ions for quantification were m/z 127.0, 91.2, 315.9 and 276.2 for 
      4-chlorophenoxyacetic acid, 6-benzylaminopurine, enrofloxacin and norfloxacin, 
      respectively. The calibration curves showed good linearity in the range of 5 - 
      200 microg/L with correlation coefficients more than 0.995. The limits of 
      detection (LODs) were 1 microg/kg and the limits of quantification (LOQs) were 5 
      microg/kg for the four compounds spiked in mung bean sprouts and mung beans. The 
      recoveries of the four compounds spiked at three levels of 5.0, 10.0 and 20.0 
      microg/kg ranged from 70% to 91%, with the relative standard deviations (RSDs) 
      less than 14%. The method established is accurate, sensitive, simple, and has 
      considerable advantages in the analysis of the four kinds of illegal additive 
      residues in sprouts and beans simultaneously.
FAU - Liu, Han
AU  - Liu H
AD  - Animal, Plant and Food Inspection Center of Jiangsu Entry-Exit Inspection and 
      Quarantine Bureau, Nanjing 210001 China. liuhan1982@yahoo.com.cn
FAU - Wu, Bin
AU  - Wu B
FAU - Yin, Yao
AU  - Yin Y
FAU - Xu, Wei
AU  - Xu W
FAU - Gui, Qianwen
AU  - Gui Q
FAU - Yu, Keyao
AU  - Yu K
FAU - Gong, Yuxia
AU  - Gong Y
FAU - Zhao, Zengyun
AU  - Zhao Z
FAU - Lin, Hong
AU  - Lin H
FAU - Shen, Weijian
AU  - Shen W
FAU - Shen, Chongyu
AU  - Shen C
FAU - Zhang, Rui
AU  - Zhang R
LA  - chi
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Benzyl Compounds)
RN  - 0 (Fluoroquinolones)
RN  - 0 (Purines)
RN  - 2577AQ9262 (2,4-Dichlorophenoxyacetic Acid)
RN  - 3DX3XEK1BN (Enrofloxacin)
RN  - 4EMM3U5P3K (4-chlorophenoxyacetic acid)
RN  - KXG6A989PS (benzylaminopurine)
RN  - P39Y9652YJ (Kinetin)
SB  - IM
MH  - 2,4-Dichlorophenoxyacetic Acid/analogs & derivatives/analysis
MH  - Benzyl Compounds
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Enrofloxacin
MH  - Fabaceae/*chemistry
MH  - Fluoroquinolones/analysis
MH  - Food Contamination/*analysis
MH  - Kinetin/analysis
MH  - Purines
MH  - Tandem Mass Spectrometry/*methods
MH  - Vegetables/*chemistry
EDAT- 2013/05/15 06:00
MHDA- 2014/12/20 06:00
CRDT- 2013/05/15 06:00
PHST- 2013/05/15 06:00 [entrez]
PHST- 2013/05/15 06:00 [pubmed]
PHST- 2014/12/20 06:00 [medline]
AID - 10.3724/sp.j.1123.2012.07039 [doi]
PST - ppublish
SO  - Se Pu. 2013 Jan;31(1):22-6. doi: 10.3724/sp.j.1123.2012.07039.