PMID- 23667992
OWN - NLM
STAT- MEDLINE
DCOM- 20141219
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 31
IP  - 1
DP  - 2013 Jan
TI  - [Simultaneous determination of o-phthalaldehyde, p-chloro-m-xylenol and triclosan 
      in compound chemical disinfectants and daily chemicals by micellar electrokinetic 
      chromatography].
PG  - 64-70
AB  - A novel method for the separation and determination of o-phthalaldehyde (OPA), 
      p-chloro-m-xylenol (PCMX) and triclosan in daily chemicals and compound chemical 
      disinfectants in a single run by micellar electrokinetic chromatography (MEKC) 
      was established. The factors such as the buffer concentration and pH, the 
      concentration of sodium dodecyl sulfate (SDS), and the sample buffer, were 
      investigated in detail. The analysis was carried out using a 50 microm uncoated 
      capillary of 40.2 cm in total length (effective length: 30 cm). The running 
      buffer was 20 mmol/L Na2B4O7, and 80 mmol/L SDS. The sample buffer was 2 mmol/L 
      Na2B4O7-8 mmol/L SDS (without pH adjustment) containing 10% (v/v) methanol. The 
      detection wavelength was 214 nm. The relative standard deviations (RSDs) of the 
      corrected peak areas of the three components were in the range of 1.1% - 3.8%, 
      and the RSDs of migration times were less than 0.9%. The limits of detection 
      (LODs, S/N = 3) were 4.0, 0.4 and 0.4 mg/L, and the limits of quantification 
      (LOQs, S/N = 10) were 12, 1.2, and 1.2 mg/L for OPA, PCMX and triclosan, 
      respectively. The corrected peak areas and the concentrations of the three 
      components showed good linear relationship within the ranges of 12 - 2 000 mg/L, 
      1.2 - 200 mg/L and 1.2 - 200 mg/L with the correlation coefficients of 0.999 4, 
      0.999 3 and 0.999 5 for OPA, PCMX and triclosan, respectively. The method was 
      used for the determination of the three components in compound chemical 
      disinfectants, hand washing liquids, soaps and a toothpaste. The results showed 
      that the three components could be assayed in a single run with simple sample 
      pretreatment, rapidity, accuracy and low cost, and the method is convenient for 
      routine analysis.
FAU - Xie, N
AU  - Xie N
AD  - College of Sciences, Agricultural University of Hebei, Baoding 071001, China.
FAU - Ding, Xiaojing
AU  - Ding X
FAU - Song, Baohu
AU  - Song B
FAU - Li, Jia
AU  - Li J
FAU - Wang, Zhi
AU  - Wang Z
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Disinfectants)
RN  - 0 (Xylenes)
RN  - 0F32U78V2Q (chloroxylenol)
RN  - 4NM5039Y5X (Triclosan)
RN  - 643-79-8 (o-Phthalaldehyde)
SB  - IM
MH  - Chromatography, Micellar Electrokinetic Capillary/*methods
MH  - Disinfectants/*chemistry
MH  - Triclosan/*analysis
MH  - Xylenes/*analysis
MH  - o-Phthalaldehyde/*analysis
EDAT- 2013/05/15 06:00
MHDA- 2014/12/20 06:00
CRDT- 2013/05/15 06:00
PHST- 2013/05/15 06:00 [entrez]
PHST- 2013/05/15 06:00 [pubmed]
PHST- 2014/12/20 06:00 [medline]
AID - 10.3724/sp.j.1123.2012.08046 [doi]
PST - ppublish
SO  - Se Pu. 2013 Jan;31(1):64-70. doi: 10.3724/sp.j.1123.2012.08046.