PMID- 23796536 OWN - NLM STAT- MEDLINE DCOM- 20140213 LR - 20191210 IS - 1873-4235 (Electronic) IS - 0956-5663 (Linking) VI - 49 DP - 2013 Nov 15 TI - A sensitive and selective molecularly imprinted sensor combined with magnetic molecularly imprinted solid phase extraction for determination of dibutyl phthalate. PG - 367-73 LID - S0956-5663(13)00388-6 [pii] LID - 10.1016/j.bios.2013.05.054 [doi] AB - A highly sensitive and selective molecularly imprinted (MIP) sensor combined with magnetic molecularly imprinted solid phase extraction (MMISPE) was developed for the determination of dibutyl phthalate (DBP) in complex matrixes. The magnetic molecularly imprinted polymer (MMIP) was synthesized as solid phase extraction (SPE) sorbet to extract DBP from complex matrixes and as sensing element to improve the selectivity of the imprinted sensor. The morphologies of MMIP and MIP-sensor were characterized by using scanning electron microscope (SEM) and transmission electron microscopy (TEM). The electrochemical performances of MIP-sensor were investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The conditions of preconcentration, elution and electrochemical determination were studied in detail. Under the optimized experimental conditions, the response currents of the MIP-sensor exhibited a linear relationship towards DBP concentrations ranging from 1.0 x 10(-8)g/L to 1.0 x 10(-3)g/L. The limit of detection of the MMIP-sensor coupled with the MMISPE was calculated as 0.052 ng/L. The MMIP-sensor coupled with the MMISPE was applied to detect DBP in complex samples successfully. CI - Copyright (c) 2013 Elsevier B.V. All rights reserved. FAU - Zhang, Zhaohui AU - Zhang Z AD - Key laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Hunan 427000, PR China. zhaohuizhang77@163.com FAU - Luo, Lijuan AU - Luo L FAU - Cai, Rong AU - Cai R FAU - Chen, Hongjun AU - Chen H LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20130606 PL - England TA - Biosens Bioelectron JT - Biosensors & bioelectronics JID - 9001289 RN - 0 (Plasticizers) RN - 2286E5R2KE (Dibutyl Phthalate) SB - IM MH - Dibutyl Phthalate/*analysis MH - Electrochemical Techniques/methods MH - Limit of Detection MH - Magnetics/methods MH - Molecular Imprinting/*methods MH - Plasticizers/*analysis MH - Solid Phase Extraction/*methods OTO - NOTNLM OT - Combined system OT - Dibutyl phthalate OT - Imprinted sensor OT - Magnetic imprinted extraction EDAT- 2013/06/26 06:00 MHDA- 2014/02/14 06:00 CRDT- 2013/06/26 06:00 PHST- 2013/03/28 00:00 [received] PHST- 2013/05/22 00:00 [revised] PHST- 2013/05/30 00:00 [accepted] PHST- 2013/06/26 06:00 [entrez] PHST- 2013/06/26 06:00 [pubmed] PHST- 2014/02/14 06:00 [medline] AID - S0956-5663(13)00388-6 [pii] AID - 10.1016/j.bios.2013.05.054 [doi] PST - ppublish SO - Biosens Bioelectron. 2013 Nov 15;49:367-73. doi: 10.1016/j.bios.2013.05.054. Epub 2013 Jun 6.