PMID- 23858912 OWN - NLM STAT- MEDLINE DCOM- 20130801 LR - 20190715 IS - 1533-4880 (Print) IS - 1533-4880 (Linking) VI - 13 IP - 5 DP - 2013 May TI - Thermal annealing effects on the physical properties of styrenic pentablock ionomers and their electromechanical responses. PG - 3606-10 AB - Thermal annealing effect on the physical properties of two ionic (poly((t-butyl-styrene)-b-(ethylene-r-propylene)-b-(styrene-r-styrene sulfonate)-b-(ethylene-r-propylene)-b-(t-butyl-styrene (SSPB) pentablock copolymers with different ion exchange capacities (IEC; 1.5 and 2.0 meq/g) and their electromechanical responses in ionic polymer-metal composite (IPMC) devices have been investigated. The ionic SSPB formed the microphase-separated morphology on the several tens nanometer scale and the selectively sulfonated styrene middle blocks formed the ionic channels through which ions can pass in the membrane. The thermal annealing at a high temperature led to the well developed interconnectivity between adjacent ionic channels, and thus enhanced the ion conductivity and mechanical strength of membranes, resulting in an actuation enhancement of the SSPB-based ionic actuator. FAU - Lee, Jang-Woo AU - Lee JW AD - Nano Hybrids Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea. FAU - Lee, Jin Hong AU - Lee JH FAU - Kim, Minho AU - Kim M FAU - Hong, Soon Man AU - Hong SM FAU - Koo, Chong Min AU - Koo CM LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - J Nanosci Nanotechnol JT - Journal of nanoscience and nanotechnology JID - 101088195 RN - 0 (Styrenes) SB - IM MH - Elastic Modulus MH - Electric Conductivity MH - Hardness MH - Hot Temperature MH - Materials Testing MH - Nanostructures/*chemistry/*ultrastructure MH - Particle Size MH - Styrenes/*chemistry MH - Tensile Strength EDAT- 2013/07/19 06:00 MHDA- 2013/08/02 06:00 CRDT- 2013/07/18 06:00 PHST- 2013/07/18 06:00 [entrez] PHST- 2013/07/19 06:00 [pubmed] PHST- 2013/08/02 06:00 [medline] AID - 10.1166/jnn.2013.7245 [doi] PST - ppublish SO - J Nanosci Nanotechnol. 2013 May;13(5):3606-10. doi: 10.1166/jnn.2013.7245.