PMID- 23892160
OWN - NLM
STAT- MEDLINE
DCOM- 20140401
LR  - 20221207
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 260
DP  - 2013 Sep 15
TI  - Kinetic modeling on CO(2) capture using basic oxygen furnace slag coupled with 
      cold-rolling wastewater in a rotating packed bed.
PG  - 937-46
LID - S0304-3894(13)00452-4 [pii]
LID - 10.1016/j.jhazmat.2013.06.052 [doi]
AB  - In this study, direct and indirect carbonation of basic oxygen furnace slag 
      (BOFS) coupled with cold-rolling wastewater (CRW) was carried out via a rotating 
      packed bed (RPB). The solid products were qualitatively characterized by scanning 
      electron microscopy (SEM) and X-ray diffraction (XRD) and quantitatively analyzed 
      with thermogravimetric analysis (TGA). The leachate was analyzed with inductively 
      coupled plasma-optical emission spectroscopy (ICP-OES). The results indicate that 
      the maximum achievable carbonation conversion (MACC) of BOFS was 90.7%, 
      corresponding to a capture capacity of 0.277 g CO(2)/g of BOFS, by direct 
      carbonation with CRW under a rotation speed of 750 rpm at 30  degrees C for 20 min. In 
      addition, CO(2) mass balance among the gas, liquid, and solid phases within an RPB 
      was well-developed, with an error less than 10%, to confirm the actual CO(2) 
      capture capacity of BOFS with precision and accuracy. Furthermore, a reaction 
      kinetic model based on mass balance was established to determine the reaction 
      rate constant for various liquid agents (CRW and pure water). It was concluded 
      that co-utilization of alkaline wastes including BOFS and CRW via the RPB is a 
      novel approach for both enhancing CO(2) capture capacity and reducing the 
      environmental impacts of alkaline wastes.
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Chang, E-E
AU  - Chang EE
AD  - Department of Biochemistry, Taipei Medical University, Taipei, Taiwan.
FAU - Chen, Tse-Lun
AU  - Chen TL
FAU - Pan, Shu-Yuan
AU  - Pan SY
FAU - Chen, Yi-Hung
AU  - Chen YH
FAU - Chiang, Pen-Chi
AU  - Chiang PC
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130628
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Air Pollutants)
RN  - 0 (Industrial Waste)
RN  - 0 (Ions)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
RN  - 12597-69-2 (Steel)
RN  - 142M471B3J (Carbon Dioxide)
RN  - 7440-44-0 (Carbon)
RN  - H0G9379FGK (Calcium Carbonate)
RN  - S88TT14065 (Oxygen)
SB  - IM
MH  - Air Pollutants
MH  - Calcium Carbonate/chemistry
MH  - Carbon/chemistry
MH  - Carbon Dioxide/*chemistry
MH  - Construction Materials
MH  - Equipment Design
MH  - Hydrogen-Ion Concentration
MH  - Industrial Waste
MH  - Ions
MH  - Kinetics
MH  - Microscopy, Electron, Scanning
MH  - Models, Chemical
MH  - Oxygen/*chemistry
MH  - Steel
MH  - Temperature
MH  - Thermogravimetry
MH  - Time Factors
MH  - Wastewater
MH  - Water Pollutants, Chemical/*analysis/chemistry
MH  - Water Purification/*methods
MH  - X-Ray Diffraction
OTO - NOTNLM
OT  - Accelerated carbonation
OT  - Mass balance
OT  - Mass transfer coefficient
OT  - Material balance
OT  - Reaction rate constant
EDAT- 2013/07/31 06:00
MHDA- 2014/04/02 06:00
CRDT- 2013/07/30 06:00
PHST- 2013/01/25 00:00 [received]
PHST- 2013/06/14 00:00 [revised]
PHST- 2013/06/20 00:00 [accepted]
PHST- 2013/07/30 06:00 [entrez]
PHST- 2013/07/31 06:00 [pubmed]
PHST- 2014/04/02 06:00 [medline]
AID - S0304-3894(13)00452-4 [pii]
AID - 10.1016/j.jhazmat.2013.06.052 [doi]
PST - ppublish
SO  - J Hazard Mater. 2013 Sep 15;260:937-46. doi: 10.1016/j.jhazmat.2013.06.052. Epub 
      2013 Jun 28.