PMID- 23898639
OWN - NLM
STAT- MEDLINE
DCOM- 20150708
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 31
IP  - 4
DP  - 2013 Apr
TI  - [Determination of carcinogenic aromatic amines derived from azo colorants in 
      textiles and leather by ultra high performance liquid chromatography-tandem mass 
      spectrometry].
PG  - 380-5
AB  - A rapid determination method was developed for the quantification and 
      confirmation of 22 carcinogenic aromatic amines derived from azo colorants in 
      textiles and leather by ultra high performance liquid chromatography-tandem 
      electrospray ionization mass spectrometry (UHPLC-MS/MS). The methods of EN 
      14362-1:2012 (for textiles) and ISO 17234-1:2010 (for leather) were adopted for 
      sample pretreatment, finally diluted with methanol. The target compounds were 
      separated by an Eclipse XDB-C18 RRHD column and eluted with methanol and water in 
      gradient, and then determined by positive electrospray ionization mass 
      spectrometry under multiple reaction monitoring (MRM) mode. The external standard 
      method was used for the quantitative analysis. The separation conditions, 
      fragment voltages, collision energies, etc. were optimized. The limits of 
      quantification (LOQ) were below 0.2 mg/kg for different compounds, matrix spike 
      recoveries ranged from 70% to 120% at the spiked levels of 500, 1 000 and 1 500 
      microg/L, and the relative standard deviations (RSDs) were less than 15%. The 
      proposed method is rapid, sensitive, accurate and selective.
FAU - Wen, Yuyun
AU  - Wen Y
AD  - College of Ocean and Earth Sciences, Xiamen University, Xiamen 361005, China.
FAU - Ou, Yan
AU  - Ou Y
FAU - He, Mingchao
AU  - He M
FAU - Gong, Zhenbin
AU  - Gong Z
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Amines)
RN  - 0 (Azo Compounds)
RN  - 0 (Carcinogens)
SB  - IM
MH  - Amines/*analysis
MH  - Azo Compounds
MH  - Carcinogens/analysis
MH  - *Chromatography, High Pressure Liquid
MH  - Spectrometry, Mass, Electrospray Ionization
MH  - *Tandem Mass Spectrometry
MH  - *Textiles
EDAT- 2013/08/01 06:00
MHDA- 2015/07/15 06:00
CRDT- 2013/08/01 06:00
PHST- 2013/08/01 06:00 [entrez]
PHST- 2013/08/01 06:00 [pubmed]
PHST- 2015/07/15 06:00 [medline]
AID - 10.3724/sp.j.1123.2012.10037 [doi]
PST - ppublish
SO  - Se Pu. 2013 Apr;31(4):380-5. doi: 10.3724/sp.j.1123.2012.10037.