PMID- 23900847 OWN - NLM STAT- MEDLINE DCOM- 20141024 LR - 20211021 IS - 1573-4994 (Electronic) IS - 1053-0509 (Linking) VI - 24 IP - 1 DP - 2014 Jan TI - Enhanced fluorescence of graphene oxide by well-controlled Au@SiO2 core-shell nanoparticles. PG - 137-41 LID - 10.1007/s10895-013-1279-6 [doi] AB - Graphene and graphene derivatives, including graphene oxide (GO) and reduced GO (rGO), have attracted remarkable attention in different fields due to their unique electronic, thermal, and mechanical properties, whereas the fluorescence property is rarely been studied. This paper reports on metal-enhanced fluorescence Au@SiO2 composite nanoparticles adsorbed graphene oxide nanosheets, where the silica-shell is used to control the distance between gold-core and fluorophore GO, and a positively charged polyelectrolyte poly(allylamine hydrochloride) (PAH) is used to adsorb the negatively charged silica-shell and GO by layer-by-layer assembly (LbL) approach. The silica-shell around the 80 nm gold-core can be well-controlled by ending the reaction at different times. Various analytical techniques were applied to characterize the morphology and optical characters of the as-prepared particles. A more than three-fold increase of the fluorescence intensity of GO was obtained. FAU - Li, Cuiyan AU - Li C AD - Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China, abuangle@126.com. FAU - Zhu, Yihua AU - Zhu Y FAU - Wang, Siwen AU - Wang S FAU - Zhang, Xiaoqing AU - Zhang X FAU - Yang, Xiaoling AU - Yang X FAU - Li, Chunzhong AU - Li C LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20130731 PL - Netherlands TA - J Fluoresc JT - Journal of fluorescence JID - 9201341 RN - 0 (Oxides) RN - 0 (Polyamines) RN - 30551-89-4 (polyallylamine) RN - 7440-57-5 (Gold) RN - 7631-86-9 (Silicon Dioxide) RN - 7782-42-5 (Graphite) SB - IM MH - Adsorption MH - *Fluorescence MH - Gold/*chemistry MH - Graphite/*chemistry MH - Nanoparticles/*chemistry MH - Oxides/*chemistry MH - Polyamines/chemistry MH - Silicon Dioxide/*chemistry MH - Surface Properties EDAT- 2013/08/01 06:00 MHDA- 2014/10/25 06:00 CRDT- 2013/08/01 06:00 PHST- 2013/04/03 00:00 [received] PHST- 2013/07/18 00:00 [accepted] PHST- 2013/08/01 06:00 [entrez] PHST- 2013/08/01 06:00 [pubmed] PHST- 2014/10/25 06:00 [medline] AID - 10.1007/s10895-013-1279-6 [doi] PST - ppublish SO - J Fluoresc. 2014 Jan;24(1):137-41. doi: 10.1007/s10895-013-1279-6. Epub 2013 Jul 31.