PMID- 23981871 OWN - NLM STAT- MEDLINE DCOM- 20131217 LR - 20130828 IS - 1477-8920 (Print) IS - 1477-8920 (Linking) VI - 11 IP - 3 DP - 2013 Sep TI - Inactivation of Ascaris eggs in water using hydrogen peroxide and a Fenton type nanocatalyst (FeOx/C) synthesized by a novel hybrid production process. PG - 419-29 LID - 10.2166/wh.2013.203 [doi] AB - Inactivation tests of Ascaris eggs (Ae) were performed using hydrogen peroxide and a Fenton type nanocatalyst supported on activated carbon (AC) (FeOx/C). Blank inactivation tests were also carried out using H2O2 and H2O2/AC as oxidation systems. The FeOx/C nanocatalyst was synthesized through a novel hybrid method developed in this work. The method is based on the incipient impregnation technique, using isopropyl alcohol as dissolvent and chelating agent of the iron salt and the ultrasonic method. The supported nanocatalyst contained 2.61% w/w of total iron and the support 0.2% w/w. Transmission electron microscopy (TEM)-energy dispersive spectrometer (EDS) images permitted verification of the presence of finely dispersed FeOx nanoparticles, with sizes ranging from 19 to 63 nm. SEM-EDS analysis and TEM images also showed good dispersion of iron oxide nanoparticles, most probably maghemite; gamma-Fe2O3, able to produce hydroperoxyl radical as reported in the literature. The FeOx/C nanocatalyst-H2O2 system showed an average Ae inactivation efficiency of 4.46% Ae/mg H2O2. This value is significantly higher than the result obtained using the support-H2O2 system and H2O2 alone and it is also better than data reported for the classical Fenton process (homogeneous phase) with or without UV light. FAU - Morales, Ariadna A AU - Morales AA AD - Instituto de Ingenieria, Universidad Nacional Autonoma de Mexico, Mexico. FAU - Schouwenaars, Rafael AU - Schouwenaars R FAU - Pfeiffer, Heriberto AU - Pfeiffer H FAU - Ramirez-Zamora, Rosa Maria AU - Ramirez-Zamora RM LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - J Water Health JT - Journal of water and health JID - 101185420 RN - 0 (Ferric Compounds) RN - BBX060AN9V (Hydrogen Peroxide) SB - IM MH - Animals MH - Ascaris suum/*drug effects MH - Ferric Compounds/chemical synthesis/*pharmacology MH - Hydrogen Peroxide/*pharmacology MH - Microscopy, Electron MH - Nanoparticles MH - Ovum/*drug effects MH - Parasite Egg Count MH - Water Purification/*methods EDAT- 2013/08/29 06:00 MHDA- 2013/12/18 06:00 CRDT- 2013/08/29 06:00 PHST- 2013/08/29 06:00 [entrez] PHST- 2013/08/29 06:00 [pubmed] PHST- 2013/12/18 06:00 [medline] AID - 10.2166/wh.2013.203 [doi] PST - ppublish SO - J Water Health. 2013 Sep;11(3):419-29. doi: 10.2166/wh.2013.203.