PMID- 24001665 OWN - NLM STAT- MEDLINE DCOM- 20140423 LR - 20141120 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 93 IP - 7 DP - 2013 Oct TI - Remediation of Cr(VI) from chromium slag by biocementation. PG - 1352-8 LID - S0045-6535(13)01088-6 [pii] LID - 10.1016/j.chemosphere.2013.08.008 [doi] AB - Here we demonstrate a calcifying ureolytic bacterium Bacillus sp. CS8 for the bioremediation of chromate (Cr(VI)) from chromium slag based on microbially induced calcite precipitation (MICP). A consolidated structure like bricks was prepared from chromium slags using bacterial cells, and five stage Cr(VI) sequential extraction was carried out to know their distribution pattern. Cr(VI) mobility was found to significantly be decreased in the exchangeable fraction of Cr slag and subsequently, the Cr(VI) concentration was markedly increased in carbonated fraction after bioremediation. It was found that such Cr slag bricks developed high compressive strength with low permeability. Further, leaching behavior of Cr(VI) in the Cr slag was studied by column tests and remarkable decrease in Cr(VI) concentration was noticed after bioremediation. Cr slags from columns were characterized by SEM-EDS confirming MICP process in bioremediation. The incorporation of Cr(VI) into the calcite surface forms a strong complex that leads to obstruction in Cr(VI) release into the environment. As China is facing chromium slag accidents at the regular time intervals, the technology discussed in the present study promises to provide effective and economical treatment of such sites across the country, however, it can be used globally. CI - Copyright (c) 2013 Elsevier Ltd. All rights reserved. FAU - Achal, Varenyam AU - Achal V AD - Laboratory of Environmental Pollution and Bioremediation, Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, China. FAU - Pan, Xiangliang AU - Pan X FAU - Lee, Duu-Jong AU - Lee DJ FAU - Kumari, Deepika AU - Kumari D FAU - Zhang, Daoyong AU - Zhang D LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20130831 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Soil Pollutants) RN - 0R0008Q3JB (Chromium) RN - 18540-29-9 (chromium hexavalent ion) SB - IM MH - Biodegradation, Environmental MH - China MH - Chromium/*analysis/metabolism MH - Environmental Restoration and Remediation/*methods MH - Soil Pollutants/*analysis/metabolism OTO - NOTNLM OT - Biocement OT - Bioremediation OT - Calcite OT - Chromium slag OT - Urease EDAT- 2013/09/05 06:00 MHDA- 2014/04/24 06:00 CRDT- 2013/09/05 06:00 PHST- 2013/06/10 00:00 [received] PHST- 2013/08/02 00:00 [revised] PHST- 2013/08/06 00:00 [accepted] PHST- 2013/09/05 06:00 [entrez] PHST- 2013/09/05 06:00 [pubmed] PHST- 2014/04/24 06:00 [medline] AID - S0045-6535(13)01088-6 [pii] AID - 10.1016/j.chemosphere.2013.08.008 [doi] PST - ppublish SO - Chemosphere. 2013 Oct;93(7):1352-8. doi: 10.1016/j.chemosphere.2013.08.008. Epub 2013 Aug 31.