PMID- 24038989
OWN - NLM
STAT- MEDLINE
DCOM- 20140519
LR  - 20131014
IS  - 1439-7641 (Electronic)
IS  - 1439-4235 (Linking)
VI  - 14
IP  - 15
DP  - 2013 Oct 21
TI  - A potential carcinogenic pyrene derivative under Forster resonance energy 
      transfer to various energy acceptors in nanoscopic environments.
PG  - 3581-93
LID - 10.1002/cphc.201300568 [doi]
AB  - Picosecond-resolved Forster resonance energy transfer (FRET) from various 
      vibronic bands in benzo[a]pyrene (BP) shows a strong dependency on the spectral 
      overlap of an energy acceptor in a confined environment. Our study on the dipolar 
      interactions between BP and different acceptors, including ethidium (Et), 
      acridine orange (AO), and crystal violet (CV), at the surface of a model anionic 
      micelle revealed that the Forster distance (R0) and the rate of energy transfer 
      is dependent on the individual spectral overlap of the vibronic bands of BP with 
      the absorption spectra of the different energy acceptors. The differential 
      behavior of the vibronic bands is compared with that of different dyes [quantum 
      dots (QDs)] in a "dye-blend" (mixture) under FRET to an energy acceptor. 
      Comparison of the FRET of the QDs with that of BP confirmed the independent 
      nature of the dipolar interaction of the vibronic bands with other organic 
      molecules, and the use of deconvolution techniques in the interpretation of the 
      donor-acceptor (D-A) distance was also justified. We also showed that the 
      consideration of differential FRET from the vibronic bands of BP and from the QDs 
      in the dye-blend is equally acceptable in theoretical frameworks including the 
      Infelta-Tachiya model and D-A distribution analysis in nanoenvironments.
CI  - Copyright (c) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Banerjee, Soma
AU  - Banerjee S
AD  - Department of Chemical, Biological & Macromolecular Sciences, S. N. Bose National 
      Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 
      (India).
FAU - Goswami, Nirmal
AU  - Goswami N
FAU - Pal, Samir Kumar
AU  - Pal SK
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20130826
PL  - Germany
TA  - Chemphyschem
JT  - Chemphyschem : a European journal of chemical physics and physical chemistry
JID - 100954211
RN  - 0 (Micelles)
RN  - 0 (Pyrenes)
RN  - 3417WMA06D (Benzo(a)pyrene)
RN  - 368GB5141J (Sodium Dodecyl Sulfate)
RN  - 9E0T7WFW93 (pyrene)
SB  - IM
MH  - Benzo(a)pyrene/chemistry
MH  - *Fluorescence Resonance Energy Transfer
MH  - Micelles
MH  - Pyrenes/*chemistry
MH  - Quantum Dots/chemistry
MH  - Sodium Dodecyl Sulfate/chemistry
MH  - Time Factors
OTO - NOTNLM
OT  - FRET
OT  - micelles
OT  - quantum dots
OT  - ultrafast spectroscopy
OT  - vibronic fine structures
EDAT- 2013/09/17 06:00
MHDA- 2014/05/20 06:00
CRDT- 2013/09/17 06:00
PHST- 2013/06/16 00:00 [received]
PHST- 2013/09/17 06:00 [entrez]
PHST- 2013/09/17 06:00 [pubmed]
PHST- 2014/05/20 06:00 [medline]
AID - 10.1002/cphc.201300568 [doi]
PST - ppublish
SO  - Chemphyschem. 2013 Oct 21;14(15):3581-93. doi: 10.1002/cphc.201300568. Epub 2013 
      Aug 26.