PMID- 24169703 OWN - NLM STAT- MEDLINE DCOM- 20131203 LR - 20131030 IS - 1318-0207 (Print) IS - 1318-0207 (Linking) VI - 60 IP - 3 DP - 2013 TI - Surface modification of polymers treated by various fluorinating media. PG - 495-504 AB - Fluorination processes of polymer surfaces are able to lead to drastic modifications of the surface properties without changing the bulk characteristics of the virgin material. In this paper, two types of polymers, i.e. ultrahigh molecular weight polyethylene (UHMWPE) and high density polyethylene (HDPE), are considered. The surface of these materials have been modified using two different fluorination routes, both carried out at room temperature: the direct fluorination with 10% F2 + 90% He gaseous mixtures and the radio-frequency plasma-enhanced fluorination (PEF) using either O2/CF4 mixtures or c-C4F8. The effect of these processes on the surface of the polymer samples are compared using mostly XPS results. The different components of the C1s spectra are assigned in term of CFx bonding, giving valuable information on the surface fluorination rate. FAU - Tressaud, Alain AU - Tressaud A FAU - Durand, Etienne AU - Durand E FAU - Labrugere, Christine AU - Labrugere C FAU - Kharitonov, Alexander P AU - Kharitonov AP FAU - Simbirtseva, Galina V AU - Simbirtseva GV FAU - Kharitonova, Larisa N AU - Kharitonova LN FAU - Dubois, Marc AU - Dubois M LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - Slovenia TA - Acta Chim Slov JT - Acta chimica Slovenica JID - 101247110 RN - 0 (Biocompatible Materials) RN - 0 (Polyethylenes) RN - 0 (ultra-high molecular weight polyethylene) RN - 9002-88-4 (Polyethylene) SB - IM MH - Biocompatible Materials/*chemistry MH - Cells, Cultured MH - Halogenation MH - Polyethylene/*chemistry MH - Polyethylenes/*chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Surface Properties EDAT- 2013/10/31 06:00 MHDA- 2013/12/16 06:00 CRDT- 2013/10/31 06:00 PHST- 2013/10/31 06:00 [entrez] PHST- 2013/10/31 06:00 [pubmed] PHST- 2013/12/16 06:00 [medline] AID - Tressaud-2013-3 [pii] PST - ppublish SO - Acta Chim Slov. 2013;60(3):495-504.