PMID- 24229199 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20140806 LR - 20131115 IS - 1550-2376 (Electronic) IS - 1539-3755 (Linking) VI - 88 IP - 4 DP - 2013 Oct TI - Dynamic arrest of nematic liquid-crystal colloid networks. PG - 042505 AB - We report interesting self-assembly structures of nematic liquid-crystal colloid (NLCC) networks, which are arrested during cooling from the isotropic temperature to room temperature. The NLCC is composed of sterically stabilized colloidal particles and a nematic liquid crystal (NLC) with nematic-isotropic transition temperature (T_NI) that is much higher than those of previously studied 4-Cyano-4'-pentylbiphenyl and N-(4-Methoxybenzylidene)-4-butylaniline. We find that the structure of NLCCs depends on T(NI), cooling rates, and boundary conditions, varying from cellular network to hierarchical fern structures in different length scales. Our time-lapse study shows that the transition from the cellular network to the fern structure directly corresponds to the transition from a spinodal demixing to a nucleation-and-growth mechanism. FAU - Zou, Lu AU - Zou L AD - Liquid Crystal Institute and Chemical Physics Interdisciplinary Program, Kent State University, Kent, Ohio 44242, USA. FAU - Hwang, Jeoung-Yeon AU - Hwang JY FAU - Kim, Chanjoong AU - Kim C LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20131031 PL - United States TA - Phys Rev E Stat Nonlin Soft Matter Phys JT - Physical review. E, Statistical, nonlinear, and soft matter physics JID - 101136452 EDAT- 2013/11/16 06:00 MHDA- 2013/11/16 06:01 CRDT- 2013/11/16 06:00 PHST- 2013/08/29 00:00 [received] PHST- 2013/11/16 06:00 [entrez] PHST- 2013/11/16 06:00 [pubmed] PHST- 2013/11/16 06:01 [medline] AID - 10.1103/PhysRevE.88.042505 [doi] PST - ppublish SO - Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Oct;88(4):042505. doi: 10.1103/PhysRevE.88.042505. Epub 2013 Oct 31.