PMID- 24236803 OWN - NLM STAT- MEDLINE DCOM- 20150925 LR - 20221207 IS - 1520-5851 (Electronic) IS - 0013-936X (Linking) VI - 47 IP - 23 DP - 2013 TI - Systematic approach to determination of maximum achievable capture capacity via leaching and carbonation processes for alkaline steelmaking wastes in a rotating packed bed. PG - 13677-85 LID - 10.1021/es403323x [doi] AB - Accelerated carbonation of basic oxygen furnace slag (BOFS) coupled with cold-rolling wastewater (CRW) was performed in a rotating packed bed (RPB) as a promising process for both CO2 fixation and wastewater treatment. The maximum achievable capture capacity (MACC) via leaching and carbonation processes for BOFS in an RPB was systematically determined throughout this study. The leaching behavior of various metal ions from the BOFS into the CRW was investigated by a kinetic model. In addition, quantitative X-ray diffraction (QXRD) using the Rietveld method was carried out to determine the process chemistry of carbonation of BOFS with CRW in an RPB. According to the QXRD results, the major mineral phases reacting with CO2 in BOFS were Ca(OH)2, Ca2(HSiO4)(OH), CaSiO3, and Ca2Fe1.04Al0.986O5. Meanwhile, the carbonation product was identified as calcite according to the observations of SEM, XEDS, and mappings. Furthermore, the MACC of the lab-scale RPB process was determined by balancing the carbonation conversion and energy consumption. In that case, the overall energy consumption, including grinding, pumping, stirring, and rotating processes, was estimated to be 707 kWh/t-CO2. It was thus concluded that CO2 capture by accelerated carbonation of BOFS could be effectively and efficiently performed by coutilizing with CRW in an RPB. FAU - Pan, Shu-Yuan AU - Pan SY AD - Graduate Institute of Environmental Engineering, National Taiwan University , 71 Chou-Shan Rd., Taipei City, Taiwan 10673, Taiwan (R.O.C.). FAU - Chiang, Pen-Chi AU - Chiang PC FAU - Chen, Yi-Hung AU - Chen YH FAU - Chen, Chun-Da AU - Chen CD FAU - Lin, Hsun-Yu AU - Lin HY FAU - Chang, E-E AU - Chang EE LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20131115 PL - United States TA - Environ Sci Technol JT - Environmental science & technology JID - 0213155 RN - 0 (Carbonates) RN - 0 (Industrial Waste) RN - 0 (Waste Water) RN - 12597-69-2 (Steel) RN - 142M471B3J (Carbon Dioxide) RN - H0G9379FGK (Calcium Carbonate) SB - IM MH - Calcium Carbonate/chemistry MH - Carbon Dioxide/chemistry/*isolation & purification MH - Carbonates/chemistry MH - Industrial Waste/*analysis MH - Kinetics MH - Microscopy, Electron, Scanning MH - Models, Chemical MH - *Steel MH - Wastewater/*chemistry MH - Water Purification/*methods MH - X-Ray Diffraction EDAT- 2013/11/19 06:00 MHDA- 2015/09/26 06:00 CRDT- 2013/11/19 06:00 PHST- 2013/11/19 06:00 [entrez] PHST- 2013/11/19 06:00 [pubmed] PHST- 2015/09/26 06:00 [medline] AID - 10.1021/es403323x [doi] PST - ppublish SO - Environ Sci Technol. 2013;47(23):13677-85. doi: 10.1021/es403323x. Epub 2013 Nov 15.