PMID- 24252650
OWN - NLM
STAT- MEDLINE
DCOM- 20140527
LR  - 20191210
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1321
DP  - 2013 Dec 20
TI  - Determination of off-flavor compounds, 2-methylisoborneol and geosmin, in salmon 
      fillets using stir bar sorptive extraction-thermal desorption coupled with gas 
      chromatography-mass spectrometry.
PG  - 133-6
LID - S0021-9673(13)01638-5 [pii]
LID - 10.1016/j.chroma.2013.10.038 [doi]
AB  - A sensitive and solvent-less method for the determination of musty and earthy 
      off-flavor compounds, 2-methylisoborneol (MIB) and geosmin (GSM), in salmon 
      tissue was developed using stir bar sorptive extraction-thermal desorption 
      coupled with gas chromatography-mass spectrometry (SBSE-TD-GCMS). MIB and GSM 
      were solid phase extracted using polydimethylsiloxane (PDMS) coated stir bars, 
      analyzed by gas chromatography, and detected in full scan mode of mass selective 
      detector (MSD). Using this method, the calibration curves of MIB and GSM were 
      linear in the range of 0.3-100ng/L, with a correlation coefficient above 0.999 
      and RSDs less than 4% (n=4). The limit of detection (LOD, S/N=3, n=6) and limit 
      of quantification (LOQ, S/N=10, n=6) of MIB and GSM were both  approximately 0.3 and 1ng/L, 
      respectively. The recoveries of MIB and GSM were 22% and 29% by spike in 30ng/L 
      standard compounds, 23% and 30% by spike-in 100ng/L standard compounds in salmon 
      tissue samples with good precision (<8% of RSDs, n=6), respectively. The 
      recoveries of MIB and GSM were better than reported methodologies using SPME 
      fibres (<10%) in fish tissue samples. This method was successfully applied to 
      monitor and characterize depurated salmon fillet samples (0, 3, 6 and 10 days).
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Ruan, E D
AU  - Ruan ED
AD  - Lacombe Research Centre, Agriculture and Agri-Food Canada, 6000 C&E Trail, 
      Lacombe, AB T4L 1W1, Canada.
FAU - Aalhus, J L
AU  - Aalhus JL
FAU - Summerfelt, S T
AU  - Summerfelt ST
FAU - Davidson, J
AU  - Davidson J
FAU - Swift, B
AU  - Swift B
FAU - Juarez, M
AU  - Juarez M
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PT  - Validation Study
DEP - 20131016
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Camphanes)
RN  - 0 (Naphthols)
RN  - 2371-42-8 (2-methylisoborneol)
RN  - MYW912WXJ4 (geosmin)
SB  - IM
MH  - Animals
MH  - Camphanes/*analysis
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Limit of Detection
MH  - Naphthols/*analysis
MH  - *Salmon
MH  - Seafood/*analysis
OTO - NOTNLM
OT  - Geosmin and 2-methylisoborneol
OT  - Salmon fillets
OT  - Stir bar sorptive extraction
OT  - Thermal desorption coupled with gas chromatography-mass spectrometry
EDAT- 2013/11/21 06:00
MHDA- 2014/05/28 06:00
CRDT- 2013/11/21 06:00
PHST- 2013/08/02 00:00 [received]
PHST- 2013/10/08 00:00 [revised]
PHST- 2013/10/09 00:00 [accepted]
PHST- 2013/11/21 06:00 [entrez]
PHST- 2013/11/21 06:00 [pubmed]
PHST- 2014/05/28 06:00 [medline]
AID - S0021-9673(13)01638-5 [pii]
AID - 10.1016/j.chroma.2013.10.038 [doi]
PST - ppublish
SO  - J Chromatogr A. 2013 Dec 20;1321:133-6. doi: 10.1016/j.chroma.2013.10.038. Epub 
      2013 Oct 16.