PMID- 24268175 OWN - NLM STAT- MEDLINE DCOM- 20140925 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 104 DP - 2014 Jun TI - In planta passive sampling devices for assessing subsurface chlorinated solvents. PG - 149-54 LID - S0045-6535(13)01544-0 [pii] LID - 10.1016/j.chemosphere.2013.10.084 [doi] AB - Contaminant concentrations in trees have been used to delineate groundwater contaminant plumes (i.e., phytoscreening); however, variability in tree composition hinders accurate measurement of contaminant concentrations in planta, particularly for long-term monitoring. This study investigated in planta passive sampling devices (PSDs), termed solid phase samplers (SPSs) to be used as a surrogate tree core. Characteristics studied for five materials included material-air partitioning coefficients (Kma) for chlorinated solvents, sampler equilibration time and field suitability. The materials investigated were polydimethylsiloxane (PDMS), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), polyoxymethylene (POM) and plasticized polyvinyl chloride (PVC). Both PDMS and LLDPE samplers demonstrated high partitioning coefficients and diffusivities and were further tested in greenhouse experiments and field trials. While most of the materials could be used for passive sampling, the PDMS SPSs performed best as an in planta sampler. Such a sampler was able to accurately measure trichloroethylene (TCE) and tetrachloroethylene (PCE) concentrations while simultaneously incorporating simple operation and minimal impact to the surrounding property and environment. CI - Copyright (c) 2013 Elsevier Ltd. All rights reserved. FAU - Shetty, Mikhil K AU - Shetty MK AD - Missouri University of Science and Technology, Civil, Architectural and Environmental Engineering Department, 1401 N. Pine St., Rolla, MO 65409, United States. FAU - Limmer, Matt A AU - Limmer MA AD - Missouri University of Science and Technology, Civil, Architectural and Environmental Engineering Department, 1401 N. Pine St., Rolla, MO 65409, United States. Electronic address: malqn3@mst.edu. FAU - Waltermire, Kendra AU - Waltermire K AD - Missouri University of Science and Technology, Civil, Architectural and Environmental Engineering Department, 1401 N. Pine St., Rolla, MO 65409, United States. FAU - Morrison, Glenn C AU - Morrison GC AD - Missouri University of Science and Technology, Civil, Architectural and Environmental Engineering Department, 1401 N. Pine St., Rolla, MO 65409, United States. FAU - Burken, Joel G AU - Burken JG AD - Missouri University of Science and Technology, Civil, Architectural and Environmental Engineering Department, 1401 N. Pine St., Rolla, MO 65409, United States. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20131120 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Dimethylpolysiloxanes) RN - 0 (Solvents) RN - 0 (Water Pollutants, Chemical) RN - 290YE8AR51 (Trichloroethylene) RN - 63148-62-9 (baysilon) RN - 9002-88-4 (Polyethylene) RN - TJ904HH8SN (Tetrachloroethylene) SB - IM MH - Dimethylpolysiloxanes/chemistry MH - Environmental Monitoring/*instrumentation MH - Equipment Design MH - Groundwater/analysis MH - Halogenation MH - Polyethylene/chemistry MH - Solvents/*analysis MH - Tetrachloroethylene/*analysis MH - Trees/*chemistry MH - Trichloroethylene/*analysis MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Chlorinated solvents OT - Passive sampling OT - Phytoscreening OT - Polydimethylsiloxane EDAT- 2013/11/26 06:00 MHDA- 2014/09/26 06:00 CRDT- 2013/11/26 06:00 PHST- 2013/07/01 00:00 [received] PHST- 2013/09/15 00:00 [revised] PHST- 2013/10/30 00:00 [accepted] PHST- 2013/11/26 06:00 [entrez] PHST- 2013/11/26 06:00 [pubmed] PHST- 2014/09/26 06:00 [medline] AID - S0045-6535(13)01544-0 [pii] AID - 10.1016/j.chemosphere.2013.10.084 [doi] PST - ppublish SO - Chemosphere. 2014 Jun;104:149-54. doi: 10.1016/j.chemosphere.2013.10.084. Epub 2013 Nov 20.