PMID- 24283329
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20141001
LR  - 20140115
IS  - 1365-2818 (Electronic)
IS  - 0022-2720 (Linking)
VI  - 253
IP  - 2
DP  - 2014 Feb
TI  - Atomic force microscopic study of the structure of high-density polyethylene 
      deformed in liquid medium by crazing mechanism.
PG  - 151-60
LID - 10.1111/jmi.12104 [doi]
AB  - A procedure has been developed for the direct atomic force microscopic (AFM) 
      examination of the native structure of high-density polyethylene (HDPE) deformed 
      in an adsorption-active liquid medium (AALM) by the crazing mechanism. The AFM 
      investigation has been carried out in the presence of a liquid medium under 
      conditions preventing deformed films from shrinkage. Deformation of HDPE in AALM 
      has been shown to proceed through the delocalized crazing mechanism and result in 
      the development of a fibrillar-porous structure. The structural parameters of the 
      crazed polymer have been determined. The obtained AFM images demonstrate a 
      nanosized nonuniformity of the deformation and enable one to observe the 
      structural rearrangements that take place in the deformed polymer after removal 
      of the liquid medium and stress relaxation. A structural similarity has been 
      revealed between HDPE deformed in the AALM and hard elastic polymers.
CI  - (c) 2013 The Authors Journal of Microscopy (c) 2013 Royal Microscopical Society.
FAU - Bagrov, D V
AU  - Bagrov DV
AD  - Faculty of Chemistry, M. V. Lomonosov Moscow State University, Moscow, Russia.
FAU - Yarysheva, A Y
AU  - Yarysheva AY
FAU - Rukhlya, E G
AU  - Rukhlya EG
FAU - Yarysheva, L M
AU  - Yarysheva LM
FAU - Volynskii, A L
AU  - Volynskii AL
FAU - Bakeev, N F
AU  - Bakeev NF
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20131127
PL  - England
TA  - J Microsc
JT  - Journal of microscopy
JID - 0204522
OTO - NOTNLM
OT  - Atomic force microscopy
OT  - crazing
OT  - fibrillar-porous structure of high-density polyethylene
OT  - high-density polyethylene
EDAT- 2013/11/29 06:00
MHDA- 2013/11/29 06:01
CRDT- 2013/11/29 06:00
PHST- 2013/04/04 00:00 [received]
PHST- 2013/11/06 00:00 [accepted]
PHST- 2013/11/29 06:00 [entrez]
PHST- 2013/11/29 06:00 [pubmed]
PHST- 2013/11/29 06:01 [medline]
AID - 10.1111/jmi.12104 [doi]
PST - ppublish
SO  - J Microsc. 2014 Feb;253(2):151-60. doi: 10.1111/jmi.12104. Epub 2013 Nov 27.