PMID- 24292372
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20140918
LR  - 20140129
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 43
IP  - 8
DP  - 2014 Feb 28
TI  - Organogallium- and organozinc-rich palladium and platinum clusters.
PG  - 3114-20
LID - 10.1039/c3dt53003e [doi]
AB  - The heteroleptic, binuclear compounds [M2(GaCp*)3(PMe3)2] (M = Pd: 1a, Pt: 1b, 
      Cp* = pentamethylcyclopentadienyl) can be obtained if [Pd2(dvds)3] (dvds = 
      1,3-divinyl-1,1,3,3-tetramethyldisiloxane) or [Pt(COD)2] (COD = cyclooctadiene) 
      were treated with a 3 : 2 ratio of GaCp* and PMe3. A trinuclear complex 
      [Pd3(GaCp*)3(PMe3)3] (2) was isolated from in situ prepared [Pd(PMe3)2Me2] and 
      treatment with GaCp*. The new complexes were used as starting compounds for 
      selective Ga/Zn exchange reactions to afford the dinuclear palladium compound 
      [Pd2(ZnCp*)(ZnMe)3(PMe3)5] (3a) and the mononuclear platinum compound 
      [Pt(ZnCp*)2(ZnMe)2(PMe3)2] (3b). The effects of a final transition metal count in 
      organozinc ligated compounds and stabilization of Lewis acidic fragments like 
      [Pd(PPh3)3], [Ni(C2H4)3] or [Mo(CO)5] were presented and discussed. All compounds 
      have been fully characterized by (1)H, (13)C, and (31)P NMR spectroscopy, mass 
      spectrometry using a liquid injection field desorption ionization (LIFDI) method, 
      elemental analysis, and single crystal X-ray diffraction studies and the 
      coordination polyhedra were analysed by the method of continuous shape measure 
      (CShM).
FAU - Molon, Mariusz
AU  - Molon M
AD  - Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universitat 
      Bochum, Universitatsstrasse 150, 44780, Bochum, Germany. roland.fischer@rub.de.
FAU - Gemel, Christian
AU  - Gemel C
FAU - Fischer, Roland A
AU  - Fischer RA
LA  - eng
PT  - Journal Article
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2013/12/03 06:00
MHDA- 2013/12/03 06:01
CRDT- 2013/12/03 06:00
PHST- 2013/12/03 06:00 [entrez]
PHST- 2013/12/03 06:00 [pubmed]
PHST- 2013/12/03 06:01 [medline]
AID - 10.1039/c3dt53003e [doi]
PST - ppublish
SO  - Dalton Trans. 2014 Feb 28;43(8):3114-20. doi: 10.1039/c3dt53003e.