PMID- 24300087
OWN - NLM
STAT- MEDLINE
DCOM- 20140922
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1323
DP  - 2014 Jan 3
TI  - Preparation of monodispersed macroporous core-shell molecularly imprinted 
      particles and their application in the determination of 2,4-dichlorophenoxyacetic 
      acid.
PG  - 11-7
LID - S0021-9673(13)01756-1 [pii]
LID - 10.1016/j.chroma.2013.11.002 [doi]
AB  - Porous polymers have aroused extensive attention due to their controllable porous 
      structure in favor of mass transfer and binding capacity. In this work, the novel 
      macroporous core-shell molecularly imprinted polymers (MIP) for selective 
      recognition of 2,4-dichlorophenoxyacetic acid (2,4-D) were prepared by surface 
      initiated atom transfer radical polymerization (si-ATRP). By using one-step 
      swelling and polymerization method, the monodispersed macroporous poly(glycidyl 
      methacrylate) (PGMA) particles were synthesized and used as supporting matrix for 
      preparing surface MIP particles (PGMA@MIP). Thanks to the inner and outer 
      surface-located binding cavities and the macroporous structure, the PGMA@MIPs 
      revealed desirable efficiency for template removal and mass transfer, and thus 
      excellent accessibility and affinity toward template 2,4-D. Moreover, PGMA@MIPs 
      exhibited much higher selectivity toward 2,4-D than PGMA@NIPs. PGMA@MIP particles 
      were directly used to selectively enrich 2,4-D from tap water and the recoveries 
      of 2,4-D were obtained as 90.0-93.4% with relative standard division of 3.1-3.4% 
      (n=3). The macroporous PGMA@MIPs also possessed steady and excellent reusable 
      performance for 2,4-D in four extraction/stripping cycles. This novel macroporous 
      core-shell imprinted material may become a powerful tool for rapid and efficient 
      enrichment and separation of target compounds from the complicated samples.
CI  - Copyright (c) 2013 Elsevier B.V. All rights reserved.
FAU - Liu, Yongliang
AU  - Liu Y
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China.
FAU - He, Yonghuan
AU  - He Y
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China.
FAU - Jin, Yulong
AU  - Jin Y
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China.
FAU - Huang, Yanyan
AU  - Huang Y
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China.
FAU - Liu, Guoquan
AU  - Liu G
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China.
FAU - Zhao, Rui
AU  - Zhao R
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Lab of Analytical 
      Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of 
      Sciences, Beijing 100190, China. Electronic address: zhaorui@iccas.ac.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20131108
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Epoxy Compounds)
RN  - 0 (Methacrylates)
RN  - 0 (Polymers)
RN  - 2577AQ9262 (2,4-Dichlorophenoxyacetic Acid)
RN  - R8WN29J8VF (glycidyl methacrylate)
SB  - IM
MH  - 2,4-Dichlorophenoxyacetic Acid/*analysis
MH  - Absorption
MH  - Epoxy Compounds/*chemical synthesis/*chemistry
MH  - Kinetics
MH  - Methacrylates/*chemical synthesis/*chemistry
MH  - Microscopy, Electron
MH  - *Molecular Imprinting
MH  - Polymerization
MH  - Polymers/*chemical synthesis/chemistry
MH  - Porosity
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Water Supply
OTO - NOTNLM
OT  - 2,4-Dichlorophenoxyacetic acid
OT  - Atom transfer radical polymerization
OT  - Core-shell molecularly imprinted polymer
OT  - Macroporous structure
OT  - Poly(glycidyl methacrylate) particles
EDAT- 2013/12/05 06:00
MHDA- 2014/09/23 06:00
CRDT- 2013/12/05 06:00
PHST- 2013/09/01 00:00 [received]
PHST- 2013/10/31 00:00 [revised]
PHST- 2013/11/01 00:00 [accepted]
PHST- 2013/12/05 06:00 [entrez]
PHST- 2013/12/05 06:00 [pubmed]
PHST- 2014/09/23 06:00 [medline]
AID - S0021-9673(13)01756-1 [pii]
AID - 10.1016/j.chroma.2013.11.002 [doi]
PST - ppublish
SO  - J Chromatogr A. 2014 Jan 3;1323:11-7. doi: 10.1016/j.chroma.2013.11.002. Epub 
      2013 Nov 8.