PMID- 24392631
OWN - NLM
STAT- MEDLINE
DCOM- 20150708
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 31
IP  - 9
DP  - 2013 Sep
TI  - [Determination of environmental estrogens in cow feed and soil by high 
      performance liquid chromatography-tandem mass spectrometry].
PG  - 908-13
AB  - An analytical method was developed for the determination of the residues of five 
      environmental estrogens, including estriol, estradiol, estrone, bisphenol A and 
      diethylstilbestrol, in the cow feed and soil by solid phase extraction (SPE) and 
      high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The 
      important parameters which affect the determination efficiency such as the mobile 
      phase, the condition of mass spectrometry and solid phase extraction column were 
      optimized. The optimal determination conditions were as follows: the sample was 
      extracted with acetonitrile at first, then cleaned-up with an NH2-SPE column, and 
      an Acquity UPLC HSS T3 column was selected to separate the analytes. 
      Acetonitrile-methanol (4: 1, v/v) and 0.01% ammonia aqueous solution were used as 
      the mobile phase by gradient elution in the negative mode. The limits of 
      detection (LOD, S/N = 3) were 0.06 - 0.22 microg/kg. The overall recoveries 
      varied from 81.70% to 102.20%, and the relative standard deviations (RSDs) were 
      all less than 10.00%. This method is simple, sensitive and accurate, and suitable 
      for the determination of environmental estrogens in cow feed and soil.
FAU - Li, Xue
AU  - Li X
AD  - College of Food Science and Technology, Dalian Polytechnic University, Dalian 
      116034, China.
FAU - Mu, Guangqing
AU  - Mu G
AD  - College of Food Science and Technology, Dalian Polytechnic University, Dalian 
      116034, China.
FAU - Chen, Lijun
AU  - Chen L
AD  - College of Food Science and Technology, Dalian Polytechnic University, Dalian 
      116034, China.
FAU - Jiang, Tiemin
AU  - Jiang T
AD  - Beijing Sanyuan Foods Co., Ltd., Beijing 100076, China.
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Estrogens)
RN  - 0 (Phenols)
RN  - 0 (Soil)
RN  - 2DI9HA706A (Estrone)
RN  - 4TI98Z838E (Estradiol)
RN  - 731DCA35BT (Diethylstilbestrol)
RN  - FB33469R8E (Estriol)
RN  - MLT3645I99 (bisphenol A)
SB  - IM
MH  - Animal Feed/*analysis
MH  - Animals
MH  - Benzhydryl Compounds
MH  - Cattle
MH  - *Chromatography, High Pressure Liquid
MH  - Diethylstilbestrol
MH  - Estradiol
MH  - Estriol
MH  - Estrogens/*analysis
MH  - Estrone
MH  - Phenols
MH  - Soil/*chemistry
MH  - Solid Phase Extraction
MH  - *Tandem Mass Spectrometry
EDAT- 2014/01/08 06:00
MHDA- 2015/07/15 06:00
CRDT- 2014/01/08 06:00
PHST- 2014/01/08 06:00 [entrez]
PHST- 2014/01/08 06:00 [pubmed]
PHST- 2015/07/15 06:00 [medline]
AID - 10.3724/sp.j.1123.2013.02033 [doi]
PST - ppublish
SO  - Se Pu. 2013 Sep;31(9):908-13. doi: 10.3724/sp.j.1123.2013.02033.