PMID- 24528843
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20141003
LR  - 20140217
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 814
DP  - 2014 Mar 3
TI  - Reactive extractive electrospray ionization tandem mass spectrometry for 
      sensitive detection of tetrabromobisphenol A derivatives.
PG  - 49-54
LID - S0003-2670(14)00100-7 [pii]
LID - 10.1016/j.aca.2014.01.035 [doi]
AB  - Sensitive detection of tetrabromobisphenol A (TBBPA) and its derivatives, a group 
      of emerging toxic contaminants, is highly necessitated in environmental 
      investigation. Herein a novel analytical strategy based on reactive extractive 
      electrospray ionization (EESI) tandem mass spectrometry for detection of 
      tetrabromobisphenol A bis(2-hydroxyethyl ether) (TBBPA-BHEE), tetrabromobisphenol 
      A bis(glycidyl ether) (TBBPA-BGE), tetrabromobisphenol A bis(allylether) 
      (TBBPA-BAE), and tetrabromobisphenol S bis(allylether) (TBBPS-BAE) in industrial 
      waste water samples was developed. Active silver cations (Ag(+)), generated by 
      electrospraying a silver nitrate methanol solution (10 mg L(-1)), collides the 
      neutral TBBPA derivatives molecules in the EESI source to form [M+Ag](+) 
      complexes of the analytes under the ambient conditions. Upon collision-induced 
      dissociation (CID), characteristic fragments of the [M+Ag](+) complexes were 
      identified for confident and sensitive detection of the four TBBPA derivatives. 
      Under the optimized experimental conditions, the instrumental limits of detection 
      (LODs) of TBBPA-BHEE, TBBPA-BGE, TBBPA-BAE and TBBPS-BAE were 0.37, 0.050, 0.76, 
      and 4.6 mug L(-1), respectively. The linear ranges extended to 1000 mug L(-1) 
      (R(2)>/=0.9919), and the relative standard deviations (RSDs), inter-day variation 
      and intra-day variation were less than 7.8% (n=9), 10.0% (n=5), and 14.8% (n=1 
      per day for 5 days) for all derivatives. TBBPA derivative manufacturing 
      industrial waste water, river water and tap water samples were fast analyzed with 
      the proposed method. The contents of TBBPA derivatives were various in the 
      collected samples, with the highest 19.9+/-0.3 mug L(-1) of TBBPA-BAE in the waste 
      water samples.
CI  - Copyright (c) 2014 Elsevier B.V. All rights reserved.
FAU - Tian, Yong
AU  - Tian Y
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Chen, Jian
AU  - Chen J
AD  - Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, College of 
      Chemistry, Biology and Material Sciences, East China Institute of Technology, 
      Nanchang, 330013, China.
FAU - Ouyang, Yong-zhong
AU  - Ouyang YZ
AD  - Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, College of 
      Chemistry, Biology and Material Sciences, East China Institute of Technology, 
      Nanchang, 330013, China.
FAU - Qu, Guang-bo
AU  - Qu GB
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Liu, Ai-feng
AU  - Liu AF
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Wang, Xue-mei
AU  - Wang XM
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Liu, Chun-xiao
AU  - Liu CX
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
FAU - Shi, Jian-bo
AU  - Shi JB
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China. Electronic address: jbshi@rcees.ac.cn.
FAU - Chen, Huan-wen
AU  - Chen HW
AD  - Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, College of 
      Chemistry, Biology and Material Sciences, East China Institute of Technology, 
      Nanchang, 330013, China.
FAU - Jiang, Gui-bin
AU  - Jiang GB
AD  - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China.
LA  - eng
PT  - Journal Article
DEP - 20140119
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
OTO - NOTNLM
OT  - Mass spectrometry
OT  - Reactive ionization
OT  - Silver ion
OT  - Tetrabromobisphenol A derivatives
OT  - Waste water
EDAT- 2014/02/18 06:00
MHDA- 2014/02/18 06:01
CRDT- 2014/02/18 06:00
PHST- 2013/10/29 00:00 [received]
PHST- 2014/01/09 00:00 [revised]
PHST- 2014/01/10 00:00 [accepted]
PHST- 2014/02/18 06:00 [entrez]
PHST- 2014/02/18 06:00 [pubmed]
PHST- 2014/02/18 06:01 [medline]
AID - S0003-2670(14)00100-7 [pii]
AID - 10.1016/j.aca.2014.01.035 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2014 Mar 3;814:49-54. doi: 10.1016/j.aca.2014.01.035. Epub 2014 
      Jan 19.