PMID- 24566970
OWN - NLM
STAT- MEDLINE
DCOM- 20150506
LR  - 20211021
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 21
IP  - 11
DP  - 2014
TI  - Determination of picogram quantities of chlortoluron in soil samples by 
      luminol-chitosan chemiluminescence system.
PG  - 7204-10
LID - 10.1007/s11356-014-2646-9 [doi]
AB  - Based on the enhancing effect of chitosan (CS) on luminol-dissolved oxygen 
      chemiluminescence (CL) reaction, a flow injection (FI) luminol-CS CL system was 
      established. It was found that the increase of CL intensity was proportional to 
      the concentrations of CS ranging from 0.7 to 10.0 mumol l(-1). In the presence of 
      chlortoluron (CTU), the CL intensity of luminol-CS system could be obviously 
      inhibited and the decrements of CL intensity were linearly proportional to the 
      logarithm of CTU concentrations ranging from 0.01 to 70.0 ng ml(-1), giving the 
      limit of detection 3.0 pg ml(-1) (3sigma). At a flow rate of 2.0 ml min(-1), the 
      whole process including sampling and washing could be accomplished within 36 s, 
      offering a sample throughput of 100 h(-1). The proposed FI-CL method was 
      successfully applied to the determination of CTU in soil samples with recoveries 
      ranging from 95.0 % to 105.3 % and the relative standard deviations (RSDs) of 
      less than 4.0 %.
FAU - Li, Yajuan
AU  - Li Y
AD  - Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry 
      of Education, College of Chemistry and Materials Science, Northwest University, 
      710069, Xi'an, China.
FAU - Zhang, Jingjing
AU  - Zhang J
FAU - Xiong, Xunyu
AU  - Xiong X
FAU - Luo, Kai
AU  - Luo K
FAU - Guo, Jie
AU  - Guo J
FAU - Shen, Minxia
AU  - Shen M
FAU - Wang, Jiajia
AU  - Wang J
FAU - Song, Zhenghua
AU  - Song Z
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140226
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Phenylurea Compounds)
RN  - 0 (Soil Pollutants)
RN  - 5EXP385Q4F (Luminol)
RN  - 9012-76-4 (Chitosan)
RN  - SUW8L8G38A (chlortoluron)
SB  - IM
MH  - Chitosan/*chemistry
MH  - Hydrogen-Ion Concentration
MH  - Limit of Detection
MH  - Luminescent Measurements/instrumentation/*methods
MH  - Luminol/*chemistry
MH  - Phenylurea Compounds/*analysis
MH  - Reproducibility of Results
MH  - Soil Pollutants/*analysis
EDAT- 2014/02/26 06:00
MHDA- 2015/05/07 06:00
CRDT- 2014/02/26 06:00
PHST- 2013/11/20 00:00 [received]
PHST- 2014/02/10 00:00 [accepted]
PHST- 2014/02/26 06:00 [entrez]
PHST- 2014/02/26 06:00 [pubmed]
PHST- 2015/05/07 06:00 [medline]
AID - 10.1007/s11356-014-2646-9 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2014;21(11):7204-10. doi: 10.1007/s11356-014-2646-9. 
      Epub 2014 Feb 26.