PMID- 24576392 OWN - NLM STAT- MEDLINE DCOM- 20141118 LR - 20181202 IS - 1879-3363 (Electronic) IS - 0025-326X (Linking) VI - 81 IP - 1 DP - 2014 Apr 15 TI - Naphthalene degradation in seawater by UV irradiation: the effects of fluence rate, salinity, temperature and initial concentration. PG - 149-56 LID - S0025-326X(14)00084-8 [pii] LID - 10.1016/j.marpolbul.2014.02.003 [doi] AB - A large amount of oil pollution at sea is produced by the operational discharge of oily wastewater. The removal of polycyclic aromatic hydrocarbons (PAHs) from such sources using UV irradiation has become attractive, yet the photolysis mechanism in seawater has remained unclear. This study examines the photodegradation kinetics of naphthalene in natural seawater through a full factorial design of experiments (DOE). The effects of fluence rate, salinity, temperature and initial concentration are investigated. Results show that fluence rate, temperature and the interaction between temperature and initial concentration are the most influential factors. An increase in fluence rate can linearly promote the photodegradation process. Salinity increasingly impedes the removal of naphthalene because of the existence of free-radical scavengers and photon competitors. The results will help understand the photolysis mechanism of PAHs and develop more effective methods for treating oily seawater generated from offshore industries. CI - Copyright (c) 2014 Elsevier Ltd. All rights reserved. FAU - Jing, Liang AU - Jing L AD - Northern Region Persistent Organic Pollution Control (NRPOP) Laboratory, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL A1B 3X5, Canada. FAU - Chen, Bing AU - Chen B AD - Northern Region Persistent Organic Pollution Control (NRPOP) Laboratory, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL A1B 3X5, Canada. Electronic address: bchen@mun.ca. FAU - Zhang, Baiyu AU - Zhang B AD - Northern Region Persistent Organic Pollution Control (NRPOP) Laboratory, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL A1B 3X5, Canada. FAU - Zheng, Jisi AU - Zheng J AD - Northern Region Persistent Organic Pollution Control (NRPOP) Laboratory, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL A1B 3X5, Canada. FAU - Liu, Bo AU - Liu B AD - Northern Region Persistent Organic Pollution Control (NRPOP) Laboratory, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL A1B 3X5, Canada. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20140224 PL - England TA - Mar Pollut Bull JT - Marine pollution bulletin JID - 0260231 RN - 0 (Naphthalenes) RN - 0 (Water Pollutants, Chemical) RN - 2166IN72UN (naphthalene) SB - IM MH - Kinetics MH - Naphthalenes/*chemistry MH - Petroleum Pollution/*analysis MH - *Photolysis MH - Salinity MH - Seawater/*chemistry MH - Temperature MH - Waste Disposal, Fluid MH - Water Pollutants, Chemical/chemistry OTO - NOTNLM OT - Oil pollution OT - PAHs OT - Photodegradation kinetics OT - Seawater EDAT- 2014/03/01 06:00 MHDA- 2014/11/19 06:00 CRDT- 2014/03/01 06:00 PHST- 2013/07/23 00:00 [received] PHST- 2014/01/30 00:00 [revised] PHST- 2014/02/07 00:00 [accepted] PHST- 2014/03/01 06:00 [entrez] PHST- 2014/03/01 06:00 [pubmed] PHST- 2014/11/19 06:00 [medline] AID - S0025-326X(14)00084-8 [pii] AID - 10.1016/j.marpolbul.2014.02.003 [doi] PST - ppublish SO - Mar Pollut Bull. 2014 Apr 15;81(1):149-56. doi: 10.1016/j.marpolbul.2014.02.003. Epub 2014 Feb 24.