PMID- 24600876
OWN - NLM
STAT- MEDLINE
DCOM- 20140403
LR  - 20151119
IS  - 0959-3330 (Print)
IS  - 0959-3330 (Linking)
VI  - 35
IP  - 1-4
DP  - 2014 Jan-Feb
TI  - Photo-Fenton degradation of phenol, 2,4-dichlorophenoxyacetic acid and 
      2,4-dichlorophenol mixture in saline solution using a falling-film solar reactor.
PG  - 364-71
AB  - In this work, a saline aqueous solution of phenol, 2,4-dichlorophenoxyacetic acid 
      (2,4-D) and 2,4-dichlorophenol (2,4-DCP) was treated by the photo-Fenton process 
      in a falling-film solar reactor. The influence of the parameters such as initial 
      pH (5-7), initial concentration of Fe2+ (1-2.5mM) and rate of H202 addition 
      (1.87-3.74mmol min-1) was investigated. The efficiency of photodegradation was 
      determined from the removal of dissolved organic carbon (DOC), described by the 
      species degradation of phenol, 2,4-D and 2,4-DCP. Response surface methodology 
      was employed to assess the effects of the variables investigated, i.e. [Fe2+], 
      [H202] and pH, in the photo-Fenton process with solar irradiation. The results 
      reveal that the variables' initial concentration of Fe2+ and H202 presents 
      predominant effect on pollutants' degradation in terms of DOC removal, while pH 
      showed no influence. Under the most adequate experimental conditions, about 85% 
      DOC removal was obtained in 180 min by using a reaction system employed here, and 
      total removal of phenol, 2,4- and 2,4-DCP mixture in about 30min.
FAU - Luna, Airton J
AU  - Luna AJ
AD  - National Institute of lndustrial Property, Rio de Janeiro 20090-910, Brazil.
FAU - Nascimento, Claudio A O
AU  - Nascimento CA
AD  - Department of Chemical Engineering, University of Sao Paulo, Sao Paulo 05508-900, 
      Brazil.
FAU - Foletto, Edson Luiz
AU  - Foletto EL
AD  - Department of Chemical Engineering, Federal University of Santa Maria, Santa 
      Maria 97105-900, Brazil.
FAU - Moraes, Jose E F
AU  - Moraes JE
AD  - Department of Chemical Engineering, Federal University of Sao Paulo, Sao Paulo 
      09972-270, Brazil.
FAU - Chiavone-Filhoe, Osvaldo
AU  - Chiavone-Filhoe O
AD  - Department of Chemical Engineering, Federal University of Rio Grande do Norte, 
      Natal 59066-800, Brazil.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - England
TA  - Environ Technol
JT  - Environmental technology
JID - 9884939
RN  - 0 (Complex Mixtures)
RN  - 0 (Fenton's reagent)
RN  - 0 (Phenols)
RN  - 2577AQ9262 (2,4-Dichlorophenoxyacetic Acid)
RN  - 451W47IQ8X (Sodium Chloride)
RN  - BBX060AN9V (Hydrogen Peroxide)
RN  - E1UOL152H7 (Iron)
SB  - IM
MH  - 2,4-Dichlorophenoxyacetic Acid/*chemistry/isolation & purification/radiation 
      effects
MH  - Complex Mixtures/chemistry/isolation & purification/radiation effects
MH  - Electric Power Supplies
MH  - Equipment Design
MH  - Equipment Failure Analysis
MH  - Hydrogen Peroxide/*chemistry/radiation effects
MH  - Iron/*chemistry/radiation effects
MH  - Phenols/*chemistry/isolation & purification/radiation effects
MH  - Photochemistry/*instrumentation/methods
MH  - Sodium Chloride/*chemistry/radiation effects
MH  - *Solar Energy
MH  - Water Purification/*instrumentation
EDAT- 2014/03/08 06:00
MHDA- 2014/04/04 06:00
CRDT- 2014/03/08 06:00
PHST- 2014/03/08 06:00 [entrez]
PHST- 2014/03/08 06:00 [pubmed]
PHST- 2014/04/04 06:00 [medline]
AID - 10.1080/09593330.2013.828762 [doi]
PST - ppublish
SO  - Environ Technol. 2014 Jan-Feb;35(1-4):364-71. doi: 10.1080/09593330.2013.828762.