PMID- 24731337
OWN - NLM
STAT- MEDLINE
DCOM- 20151027
LR  - 20181202
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 158
DP  - 2014 Sep 1
TI  - Miniaturized graphene-based pipette tip extraction coupled with liquid 
      chromatography for the determination of sulfonamide residues in bovine milk.
PG  - 239-44
LID - S0308-8146(14)00274-X [pii]
LID - 10.1016/j.foodchem.2014.02.089 [doi]
AB  - A miniaturized graphene-based pipette tip extraction (M-G-PTE) method coupled 
      with liquid chromatography-ultraviolet detection was developed for rapid 
      screening of sulfadimidine, sulfachloropyridazine, sulfamonomethoxine, and 
      sulfachloropyrazine residues in bovine milk. Because of the large surface area 
      and unique chemical structure of graphene, an M-G-PTE device packed with 3.0mg 
      graphene could handle 2.0mL of milk samples at one time. This M-G-PTE device 
      showed better adsorption performance for sulfonamides (SAs) than those packed 
      with other adsorbents such as C18, HLB, SCX, PCX, and multiwalled carbon 
      nanotubes. Under the optimized conditions, good linearity was obtained in the 
      range of 0.05-6.0 mug g(-1), with a correlation coefficient (r(2)) of ⩾0.9991. The 
      recoveries at three spiking levels ranged from 90.1% to 113.5% with relative 
      standard deviations (RSDs) of ⩽3.9%. The proposed M-G-PTE method was simple, 
      economical, sensitive, and produced less organic pollution. Thus, it could be 
      applied to the rapid screening of SAs in complicated bovine milk samples.
CI  - Copyright (c) 2014 Elsevier Ltd. All rights reserved.
FAU - Yan, Hongyuan
AU  - Yan H
AD  - Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of 
      Education & College of Pharmacy, Hebei University, Baoding 071002, China. 
      Electronic address: yanhy@hbu.edu.cn.
FAU - Sun, Ning
AU  - Sun N
AD  - Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of 
      Education & College of Pharmacy, Hebei University, Baoding 071002, China.
FAU - Liu, Shijia
AU  - Liu S
AD  - Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of 
      Education & College of Pharmacy, Hebei University, Baoding 071002, China.
FAU - Row, Kyung Ho
AU  - Row KH
AD  - Department of Chemistry and Chemical Engineering, Inha University, Incheon 
      402751, Republic of Korea.
FAU - Song, Yanxue
AU  - Song Y
AD  - Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of 
      Education & College of Pharmacy, Hebei University, Baoding 071002, China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140228
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Sulfonamides)
RN  - 7782-42-5 (Graphite)
SB  - IM
MH  - Animals
MH  - Cattle
MH  - Chromatography, Liquid/*methods
MH  - Graphite/*chemistry
MH  - Milk/*chemistry
MH  - Sulfonamides/analysis/*chemistry
OTO - NOTNLM
OT  - Graphene adsorbent
OT  - Milk
OT  - Miniaturized graphene-based pipette tip extraction
OT  - Sulfonamides
EDAT- 2014/04/16 06:00
MHDA- 2015/10/28 06:00
CRDT- 2014/04/16 06:00
PHST- 2013/09/29 00:00 [received]
PHST- 2014/02/05 00:00 [revised]
PHST- 2014/02/18 00:00 [accepted]
PHST- 2014/04/16 06:00 [entrez]
PHST- 2014/04/16 06:00 [pubmed]
PHST- 2015/10/28 06:00 [medline]
AID - S0308-8146(14)00274-X [pii]
AID - 10.1016/j.foodchem.2014.02.089 [doi]
PST - ppublish
SO  - Food Chem. 2014 Sep 1;158:239-44. doi: 10.1016/j.foodchem.2014.02.089. Epub 2014 
      Feb 28.