PMID- 24734585 OWN - NLM STAT- MEDLINE DCOM- 20140513 LR - 20190715 IS - 1533-4880 (Print) IS - 1533-4880 (Linking) VI - 14 IP - 5 DP - 2014 May TI - Gamma-Fe2O3 nanospindles for environmental remediation: a study on the adsorption and desorption characteristics of acridine orange and direct red dyes. PG - 3545-51 AB - In this paper, the adsorption and desorption characteristics of two harmful dyes, i.e., acridine orange (AO; cationic dye) and direct red 81 (DR; anionic dye) from aqueous solutions onto gamma-Fe2O3 nanospindles have been investigated. The nanospindles were synthesized by facile chemical precipitation method and characterized in detail in terms of their morphological, compositional and optical properties. Batch mode experiments were conducted to examine the adsorption process by investigating several factors such as effect of pH, amount of adsorbent dose, and effect of dye concentrations. The experimental results indicated that the maximum adsorption capacity occurred at pH = 6.0 for AO and at pH = 4.0 for DR, respectively with 0.03 gm of adsorbent. Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models have been used to evaluate the ongoing adsorption. Kinetic parameters for the adsorption have also been applied. Moreover, the gamma-Fe2O3 nanospindles and the adsorbed dyes were desorbed with good performance and could be reused to absorb the dyes again. FAU - Chaudhary, Ganga Ram AU - Chaudhary GR FAU - Saharan, Priya AU - Saharan P FAU - Umar, Ahmad AU - Umar A FAU - Mehta, S K AU - Mehta SK FAU - Mor, Suman AU - Mor S LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - J Nanosci Nanotechnol JT - Journal of nanoscience and nanotechnology JID - 101088195 RN - 0 (Azo Compounds) RN - 0 (Ferric Compounds) RN - 1K09F3G675 (ferric oxide) RN - 7E49Q56PNB (Direct Red 81) RN - F30N4O6XVV (Acridine Orange) SB - IM MH - Acridine Orange/*chemistry MH - Adsorption MH - Azo Compounds/*chemistry MH - Biological Oxygen Demand Analysis MH - Environmental Restoration and Remediation/*methods MH - Ferric Compounds/*chemistry MH - Hydrogen-Ion Concentration MH - Kinetics MH - Microscopy, Electron, Transmission MH - *Nanostructures EDAT- 2014/04/17 06:00 MHDA- 2014/05/14 06:00 CRDT- 2014/04/17 06:00 PHST- 2014/04/17 06:00 [entrez] PHST- 2014/04/17 06:00 [pubmed] PHST- 2014/05/14 06:00 [medline] AID - 10.1166/jnn.2014.8715 [doi] PST - ppublish SO - J Nanosci Nanotechnol. 2014 May;14(5):3545-51. doi: 10.1166/jnn.2014.8715.