PMID- 24747853
OWN - NLM
STAT- MEDLINE
DCOM- 20150109
LR  - 20161125
IS  - 1873-3557 (Electronic)
IS  - 1386-1425 (Linking)
VI  - 129
DP  - 2014 Aug 14
TI  - Spectroscopic and structural study of some 2,5-hexanedione 
      bis(salicyloylhydrazone) complexes: crystal structures of its Ni(II) and Cu(II) 
      complexes and N-(2,5-dimethyl-1H-pyrrol-1-yl)-2-hydroxy-benzamide.
PG  - 307-13
LID - S1386-1425(14)00397-7 [pii]
LID - 10.1016/j.saa.2014.02.195 [doi]
AB  - The reaction between 2,5-hexanedione and salicylic acid hydrazide produced two 
      compounds: 2,5-hexanedione bis(salicyloylhydrazone) [HDSH] (ethanol insoluble) 
      and N-(2,5-dimethyl-1H-pyrrol-1-yl)-2-hydroxybenzamide [DPH] (ethanol soluble). 
      HDSH formed complexes with Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II) and 
      Pd(II) which are characterized by elemental analyses, spectra (IR, (1)H NMR, ESR 
      and MS), thermal and magnetic measurements. The crystals of 
      [Ni(HDSH-2H)(EtOH)(H2O)] and [Cu(HDSH-2H)] were solved having octahedral and 
      square-planar geometries, respectively. The other complexes have the formulae 
      [Co(HDSH-2H)(H2O)2], [Cu(HDSH-H)2], [Zn(HDSH-2H)(H2O)2], [Cd2(HDSH-4H)(H2O)4], 
      [Cd2(HDSH-2H)(H2O)4Cl2]; [Hg(HDSH-2H)] and [Pd2(HDSH-4H)(H2O)4]. The obtained 
      complexes are stable in air and non-hygroscopic. The magnetic moments and 
      electronic spectra of the complexes provide different geometries. The ESR spectra 
      support the mononuclear geometry for [Cu(HDSH-2H)] and [Cu(HDSH-H)2]. The thermal 
      decomposition of the complexes revealed the coordinated waters as well as the end 
      product which is in most cases the metal oxide. The crystal structure of 
      N-(2,5-dimethyl-1H-pyrrol-1-yl)-2-hydroxybenzamide is solved by X-ray technique.
CI  - Copyright (c) 2014 Elsevier B.V. All rights reserved.
FAU - Jeragh, Bakir
AU  - Jeragh B
AD  - Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 
      13060, Kuwait. Electronic address: bakir.jeragh@ku.edu.kw.
FAU - El-Asmy, Ahmed A
AU  - El-Asmy AA
AD  - Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 
      13060, Kuwait.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140313
PL  - England
TA  - Spectrochim Acta A Mol Biomol Spectrosc
JT  - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
JID - 9602533
RN  - 0 (2-hydroxybenzamide)
RN  - 0 (Benzamides)
RN  - 0 (Coordination Complexes)
RN  - 0 (Hexanones)
RN  - 0 (Hydrazones)
RN  - 789U1901C5 (Copper)
RN  - 7OV03QG267 (Nickel)
RN  - C0Z8884J3P (2,5-hexanedione)
SB  - IM
MH  - Benzamides/chemical synthesis/*chemistry
MH  - Coordination Complexes/chemical synthesis/*chemistry
MH  - Copper/*chemistry
MH  - Crystallography, X-Ray
MH  - Hexanones/chemical synthesis/*chemistry
MH  - Hydrazones/chemical synthesis/*chemistry
MH  - Models, Molecular
MH  - Nickel/*chemistry
MH  - Spectrum Analysis
OTO - NOTNLM
OT  - 2,5-Hexanedione bis(salicyloylhydrazone)
OT  - ESR
OT  - N-(2,5-dimethyl-1H-pyrrol-1-yl)-2-hydroxybenzamide
OT  - Spectra
OT  - X-ray structure
EDAT- 2014/04/22 06:00
MHDA- 2015/01/13 06:00
CRDT- 2014/04/22 06:00
PHST- 2013/12/21 00:00 [received]
PHST- 2014/01/27 00:00 [revised]
PHST- 2014/02/19 00:00 [accepted]
PHST- 2014/04/22 06:00 [entrez]
PHST- 2014/04/22 06:00 [pubmed]
PHST- 2015/01/13 06:00 [medline]
AID - S1386-1425(14)00397-7 [pii]
AID - 10.1016/j.saa.2014.02.195 [doi]
PST - ppublish
SO  - Spectrochim Acta A Mol Biomol Spectrosc. 2014 Aug 14;129:307-13. doi: 
      10.1016/j.saa.2014.02.195. Epub 2014 Mar 13.