PMID- 24757981
OWN - NLM
STAT- MEDLINE
DCOM- 20140529
LR  - 20190715
IS  - 1533-4880 (Print)
IS  - 1533-4880 (Linking)
VI  - 14
IP  - 7
DP  - 2014 Jul
TI  - Optimization of oleylamine-Fe3O4/MWCNTs nanocomposite modified GC electrode for 
      electrochemical determination of ofloxacin.
PG  - 5059-69
AB  - Iron oxide (Fe3O4) nanoparticles are prepared by nucleation method using 
      oleylamine (OLA) as the capping agent. The OLA capped Fe3O4 nanoparticles 
      (OLA-Fe3O4) are characterized by Fourier Transform Infrared (FT-IR) spectroscopy, 
      X-ray Diffraction (XRD) and High Resolution Transmission Electron Microscopic 
      (HRTEM) analysis. The morphology of the OLA-Fe3O4 nanoparticles is found to be 
      spherical with an average size of 7.5 +/- 0.5 nm. OLA-Fe3O4 nanoparticles are 
      incorporated into the carboxyl functionalized Multi-walled carbon nanotubes 
      (MWCNTs) at different 10, 20, 30, 40 and 50 wt% by ultrasonication. The optimum 
      loading of OLA-Fe3O4 nanoparticles on the MWCNTs was characterized by FTIR, Raman 
      spectroscopy, Field Emission Scanning Electron Microscopy (FESEM) and Linear 
      Sweep Voltammetry (LSV). Finally, the 40wt% of OLA-Fe3O4 nanoparticles on MWCNTs 
      was chosen as the optimum loading and this composition was used for the 
      electrochemical oxidation of ofloxacin (OFX). For determination of OFX in 
      OLA-Fe3O4/MWCNTs modified glassy carbon (GC) electrode show high sensitivity and 
      fast response. The sensitivity of the modified electrode was calculated to be 
      0.578 microAmicroM(-1) with a detection limit of 0.060 microM. The high 
      sensitivity, wider linear range, good reproducibility and the minimal surface 
      fouling make this OLA-Fe3O4/MWCNTs/GC modified electrode acts as a promising 
      platform for electrochemical determination of OFX.
FAU - Kumar, Deivasigamani Ranjith
AU  - Kumar DR
FAU - Manoj, Devaraj
AU  - Manoj D
FAU - Santhanalakshmi, Jayadevan
AU  - Santhanalakshmi J
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - United States
TA  - J Nanosci Nanotechnol
JT  - Journal of nanoscience and nanotechnology
JID - 101088195
RN  - 0 (Amines)
RN  - 0 (Anti-Bacterial Agents)
RN  - 0 (Ferric Compounds)
RN  - 0 (Nanotubes, Carbon)
RN  - 1K09F3G675 (ferric oxide)
RN  - 7440-44-0 (Carbon)
RN  - A4P49JAZ9H (Ofloxacin)
RN  - ZDQ1JWQ8DT (oleylamine)
SB  - IM
MH  - Amines/*chemistry
MH  - Anti-Bacterial Agents/*analysis
MH  - Carbon/*chemistry
MH  - Conductometry/instrumentation
MH  - *Electrodes
MH  - Equipment Design
MH  - Equipment Failure Analysis
MH  - Ferric Compounds/*chemistry
MH  - Nanotubes, Carbon/*chemistry/ultrastructure
MH  - Ofloxacin/*analysis
MH  - Transducers
EDAT- 2014/04/25 06:00
MHDA- 2014/05/30 06:00
CRDT- 2014/04/25 06:00
PHST- 2014/04/25 06:00 [entrez]
PHST- 2014/04/25 06:00 [pubmed]
PHST- 2014/05/30 06:00 [medline]
AID - 10.1166/jnn.2014.8676 [doi]
PST - ppublish
SO  - J Nanosci Nanotechnol. 2014 Jul;14(7):5059-69. doi: 10.1166/jnn.2014.8676.