PMID- 24764812 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20140425 LR - 20211021 IS - 1600-5368 (Print) IS - 1600-5368 (Electronic) IS - 1600-5368 (Linking) VI - 70 IP - Pt 2 DP - 2014 Feb 1 TI - mu-1,6,7,12-Tetra-aza-perylene-kappa(4) N (1),N (12):N (6),N (7)-bis-[chlorido-(eta(6)-p-cymene)ruthenium(II)] bis-(hexa-fluorido-phosphate) acetone disolvate. PG - m39-40 LID - 10.1107/S160053681400035X [doi] AB - In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2.2C3H6O, the binuclear Ru(II) complex dication, [RuCl(eta(6)-cym)2(mu-tape)](2+), built up by a planar 1,6,7,12-tetra-aza-perylene (tape) bridge, two eta(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexa-fluorido-phosphate anion and the asymmetric unit is completed by an acetone mol-ecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C-Hcdots, three dots, centeredO/F/Cl inter-actions. FAU - Brietzke, Thomas AU - Brietzke T AD - Universitat Potsdam, Institut fur Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany. FAU - Kassler, Daniel AU - Kassler D AD - Universitat Potsdam, Institut fur Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany. FAU - Kelling, Alexandra AU - Kelling A AD - Universitat Potsdam, Institut fur Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany. FAU - Schilde, Uwe AU - Schilde U AD - Universitat Potsdam, Institut fur Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany. FAU - Holdt, Hans-Jurgen AU - Holdt HJ AD - Universitat Potsdam, Institut fur Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany. LA - eng PT - Journal Article DEP - 20140115 PL - United States TA - Acta Crystallogr Sect E Struct Rep Online JT - Acta crystallographica. Section E, Structure reports online JID - 101089178 PMC - PMC3998251 EDAT- 2014/04/26 06:00 MHDA- 2014/04/26 06:01 PMCR- 2014/01/15 CRDT- 2014/04/26 06:00 PHST- 2013/11/29 00:00 [received] PHST- 2014/01/07 00:00 [accepted] PHST- 2014/04/26 06:00 [entrez] PHST- 2014/04/26 06:00 [pubmed] PHST- 2014/04/26 06:01 [medline] PHST- 2014/01/15 00:00 [pmc-release] AID - tk5277 [pii] AID - 10.1107/S160053681400035X [doi] PST - epublish SO - Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 15;70(Pt 2):m39-40. doi: 10.1107/S160053681400035X. eCollection 2014 Feb 1.