PMID- 24793294
OWN - NLM
STAT- MEDLINE
DCOM- 20150112
LR  - 20171116
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 274
DP  - 2014 Jun 15
TI  - The role of the anion in the toxicity of imidazolium ionic liquids.
PG  - 181-90
LID - S0304-3894(14)00197-6 [pii]
LID - 10.1016/j.jhazmat.2014.03.021 [doi]
AB  - From the environmental protection point of view, the growing interest of ionic 
      liquids in various industrial branches has raised concerns for the toxicity 
      assessment of these compounds. The paper discusses the effect of salts containing 
      the shared 1-ethyl-3-methylimidazolium [EMIM] cation as coupled with five 
      different anions: bromide [Br], nitrate [NO3], p-toluenesulfonate (tosylate) 
      [Ts], dimethylphosphate [dMP] and methanesulfonate [MS] on the growth and 
      development of higher land plants - spring barley and common radish. The 
      experiment was done according to the ISO Standard 11269-2:1995 and the OECD/OCDE 
      Guide 208/2006. As the indications of phytotoxicity, the percentage of sprouts 
      and the level of dry and fresh plant mass were used; in addition, the visual 
      assessment of any signs of damage to the examined plant species, such as growth 
      inhibition and chlorotic changes, was also made. Results of our study has proved 
      the negative impact of ILs on the tested plants and the toxic effect of 
      imidazolium salts was dependent primarily on the applied ionic liquids 
      concentration. The common radish revealed the higher tolerance to the imidazolium 
      as compared to spring barley. The anion type of ionic liquid was crucial for the 
      toxicity against common radish.
CI  - Copyright (c) 2014 Elsevier B.V. All rights reserved.
FAU - Biczak, Robert
AU  - Biczak R
AD  - Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental 
      Protection and Biotechnology, 13/15 Armii Krajowej Av., 42-200 Czestochowa, 
      Poland.
FAU - Pawlowska, Barbara
AU  - Pawlowska B
AD  - Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental 
      Protection and Biotechnology, 13/15 Armii Krajowej Av., 42-200 Czestochowa, 
      Poland.
FAU - Balczewski, Piotr
AU  - Balczewski P
AD  - Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental 
      Protection and Biotechnology, 13/15 Armii Krajowej Av., 42-200 Czestochowa, 
      Poland; Center of Molecular and Macromolecular Studies, Polish Academy of 
      Sciences, Sienkiewicza 112, 90-363 Lodz, Poland.
FAU - Rychter, Piotr
AU  - Rychter P
AD  - Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental 
      Protection and Biotechnology, 13/15 Armii Krajowej Av., 42-200 Czestochowa, 
      Poland. Electronic address: p.rychter@ajd.czest.pl.
LA  - eng
PT  - Journal Article
DEP - 20140325
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Benzenesulfonates)
RN  - 0 (Bromides)
RN  - 0 (Imidazoles)
RN  - 0 (Ionic Liquids)
RN  - 0 (Mesylates)
RN  - 0 (Nitrates)
RN  - 0 (Organophosphorus Compounds)
RN  - 12EH9M7279 (methanesulfonic acid)
RN  - HI4K2C9UEI (dimethyl phosphate)
RN  - QGV5ZG5741 (4-toluenesulfonic acid)
RN  - TVE1D62MAK (1-ethyl-3-methylimidazolium)
SB  - IM
MH  - Benzenesulfonates/toxicity
MH  - Bromides/toxicity
MH  - Hordeum/*drug effects/growth & development
MH  - Imidazoles/*chemistry/*toxicity
MH  - Ionic Liquids/*chemistry/*toxicity
MH  - Mesylates/toxicity
MH  - Nitrates/toxicity
MH  - Organophosphorus Compounds/toxicity
MH  - Raphanus/*drug effects/growth & development
MH  - Seedlings/drug effects/growth & development
OTO - NOTNLM
OT  - Dry weight
OT  - Ionic liquids
OT  - Phytotoxicity
OT  - Terrestrial plants
OT  - Yield
EDAT- 2014/05/06 06:00
MHDA- 2015/01/13 06:00
CRDT- 2014/05/06 06:00
PHST- 2013/12/03 00:00 [received]
PHST- 2014/03/08 00:00 [revised]
PHST- 2014/03/10 00:00 [accepted]
PHST- 2014/05/06 06:00 [entrez]
PHST- 2014/05/06 06:00 [pubmed]
PHST- 2015/01/13 06:00 [medline]
AID - S0304-3894(14)00197-6 [pii]
AID - 10.1016/j.jhazmat.2014.03.021 [doi]
PST - ppublish
SO  - J Hazard Mater. 2014 Jun 15;274:181-90. doi: 10.1016/j.jhazmat.2014.03.021. Epub 
      2014 Mar 25.