PMID- 24838127 OWN - NLM STAT- MEDLINE DCOM- 20150831 LR - 20211021 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 22 IP - 12 DP - 2015 Jun TI - Adsorption and desorption characteristics of methamphetamine, 3,4-methylenedioxymethamphetamine, and pseudoephedrine in soils. PG - 8855-65 LID - 10.1007/s11356-014-2940-6 [doi] AB - This work presents, for the first time, information on the adsorption-desorption characteristics of illicit drugs and precursors in soils and an estimation of their potential bioavailability. The experiment was conducted using a batch equilibrium technique for the parent drugs methamphetamine and 3,4-methylenedioxymethamphetamine (MDMA) and the precursor pseudoephedrine in three South Australian soils varying in physiochemical properties. The individual compounds exhibited different adsorption mechanisms in the test soils, and the results fitted better with the Freundlich isotherm model (r (2) >/= 0.99). The maximum adsorption capacity was recorded for pseudoephedrine (2,000 mug g(-1)). However, pseudoephedrine recorded lower organic carbon normalized adsorption coefficient values (<250 mL g(-1)), lower magnitudes of Gibb's free energy change, and higher percent desorption (73-92 %) compared to methamphetamine and MDMA. The results thus showed pseudoephedrine to be the most mobile compound in the soils under study, to have the highest availability for degradation of the three compounds, and to have the highest susceptibility to biotic degradation in test soils. FAU - Pal, Raktim AU - Pal R AD - Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes, Adelaide, South Australia, 5095, Australia. FAU - Megharaj, Mallavarapu AU - Megharaj M FAU - Kirkbride, K Paul AU - Kirkbride KP FAU - Naidu, Ravi AU - Naidu R LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20140518 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Illicit Drugs) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 44RAL3456C (Methamphetamine) RN - 7CUC9DDI9F (Pseudoephedrine) RN - KE1SEN21RM (N-Methyl-3,4-methylenedioxyamphetamine) SB - IM MH - Adsorption MH - Australia MH - Biodegradation, Environmental MH - Biological Availability MH - Illicit Drugs/*chemistry MH - Methamphetamine/*chemistry MH - N-Methyl-3,4-methylenedioxyamphetamine/*chemistry MH - Pseudoephedrine/*chemistry MH - Soil/*chemistry MH - Soil Pollutants/*chemistry MH - Thermodynamics EDAT- 2014/05/20 06:00 MHDA- 2015/09/01 06:00 CRDT- 2014/05/20 06:00 PHST- 2012/12/01 00:00 [received] PHST- 2014/04/20 00:00 [accepted] PHST- 2014/05/20 06:00 [entrez] PHST- 2014/05/20 06:00 [pubmed] PHST- 2015/09/01 06:00 [medline] AID - 10.1007/s11356-014-2940-6 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2015 Jun;22(12):8855-65. doi: 10.1007/s11356-014-2940-6. Epub 2014 May 18.