PMID- 24850700
OWN - NLM
STAT- MEDLINE
DCOM- 20150928
LR  - 20150129
IS  - 1945-239X (Electronic)
IS  - 0021-9665 (Linking)
VI  - 53
IP  - 2
DP  - 2015 Feb
TI  - Simultaneous determination of seven synthetic colorants in wine by dispersive 
      micro-solid-phase extraction coupled with reversed-phase high-performance liquid 
      chromatography.
PG  - 210-8
LID - 10.1093/chromsci/bmu042 [doi]
AB  - A novel and effective dispersive micro-solid-phase extraction (d-micro-SPE) using 
      ethanediamine-functionalized magnetic Fe3O4 polymer (EDA-MP) as an efficient 
      adsorbent in wine sample was developed. Based on this, a simple and time-saving 
      analytical method for the simultaneous determination of seven synthetic colorants 
      (i.e., tartrazine, amaranth, carmine, sunset yellow, allura red, brilliant blue 
      and erythrosine) in wine by reversed-phase high-performance liquid chromatography 
      with an ultraviolet detector was established. The experimental parameters, 
      including the chromatographic retention behavior of studied synthetic colorants, 
      the effect of the usage amount of cross-linking monomer, the effect of the usage 
      amount of EDA-MP on the recovery and the recyclability of the adsorbents, were 
      studied in detail. The results showed that the EDA-MP could be reused efficiently 
      at least six times. Under optimized conditions, the recoveries for all analytes 
      were in the range of 88.6-105.2%, with the intraday relative standard deviations 
      (RSDs) ranging from 2.1 to 8.2% and the interday RSDs ranging from 3.4 to 8.7%, 
      and all the analytes had good linearities in the tested ranges with correlation 
      coefficients (r(2)) >0.9995. The limits of quantification for seven synthetic 
      colorants were between 0.12 and 0.45 mg L(-1). The developed method was 
      successfully applied to wine samples, and it was confirmed that the EDA-MP 
      particles were highly effective d-micro-SPE materials.
CI  - (c) The Author 2014. Published by Oxford University Press. All rights reserved. For 
      Permissions, please email: journals.permissions@oup.com.
FAU - Zhang, Yun
AU  - Zhang Y
AD  - Quzhou Center for Disease Control and Prevention, Quzhou 324000, PR China.
FAU - Zhou, Hua
AU  - Zhou H
AD  - Quzhou Center for Disease Control and Prevention, Quzhou 324000, PR China.
FAU - Wang, Yougang
AU  - Wang Y
AD  - Quzhou Center for Disease Control and Prevention, Quzhou 324000, PR China.
FAU - Wu, Xianglun
AU  - Wu X
AD  - Quzhou Center for Disease Control and Prevention, Quzhou 324000, PR China.
FAU - Zhao, Yonggang
AU  - Zhao Y
AD  - Ningbo Key Laboratory of Poison Research and Control, Ningbo Municipal Center for 
      Disease Control and Prevention, Ningbo 315010, PR China zhyg91213@163.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140521
PL  - United States
TA  - J Chromatogr Sci
JT  - Journal of chromatographic science
JID - 0173225
RN  - 0 (Ethylenediamines)
RN  - 0 (Food Coloring Agents)
RN  - 60V9STC53F (ethylenediamine)
RN  - XM0M87F357 (Ferrosoferric Oxide)
SB  - IM
MH  - Adsorption
MH  - Chromatography, Reverse-Phase/*methods
MH  - Ethylenediamines/chemistry
MH  - Ferrosoferric Oxide/chemistry
MH  - Food Coloring Agents/*analysis
MH  - Limit of Detection
MH  - Linear Models
MH  - Reproducibility of Results
MH  - Solid Phase Microextraction/*methods
MH  - Wine/*analysis
EDAT- 2014/05/23 06:00
MHDA- 2015/09/29 06:00
CRDT- 2014/05/23 06:00
PHST- 2014/05/23 06:00 [entrez]
PHST- 2014/05/23 06:00 [pubmed]
PHST- 2015/09/29 06:00 [medline]
AID - bmu042 [pii]
AID - 10.1093/chromsci/bmu042 [doi]
PST - ppublish
SO  - J Chromatogr Sci. 2015 Feb;53(2):210-8. doi: 10.1093/chromsci/bmu042. Epub 2014 
      May 21.