PMID- 24932572 OWN - NLM STAT- MEDLINE DCOM- 20150109 LR - 20240404 IS - 1420-3049 (Electronic) IS - 1420-3049 (Linking) VI - 19 IP - 6 DP - 2014 Jun 13 TI - Tetrabutylammonium bromide (TBABr)-based deep eutectic solvents (DESs) and their physical properties. PG - 8011-26 LID - 10.3390/molecules19068011 [doi] AB - Density, viscosity and ionic conductivity data sets of deep eutectic solvents (DESs) formed by tetrabutylammonium bromide (TBABr) paired with ethlyene glycol, 1,3-propanediol, 1,5-pentanediol and glycerol hydrogen bond donors (HBDs) are reported. The properties of DES were measured at temperatures between 303 K and 333 K for HBD percentages of 66.7% to 90%. The effects of HBDs under different temperature and percentages are systematically analyzed. As expected, the measured density and viscosity of the studied DESs decreased with an increase in temperature, while ionic conductivity increases with temperature. In general, DESs made of TBABr and glycerol showed the highest density and viscosity and the lowest ionic conductivity when compared to other DESs. The presence of an extra hydroxyl group on glycerol in a DES affected the properties of the DES. FAU - Yusof, Rizana AU - Yusof R AD - Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang,Selangor, Malaysia. rizanayusof@gmail.com. FAU - Abdulmalek, Emilia AU - Abdulmalek E AD - Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang,Selangor, Malaysia. emilia@upm.edu.my. FAU - Sirat, Kamaliah AU - Sirat K AD - Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang,Selangor, Malaysia. kamaliah@upm.edu.my. FAU - Rahman, Mohd Basyaruddin Abdul AU - Rahman MB AD - Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang,Selangor, Malaysia. basya@upm.edu.my. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20140613 PL - Switzerland TA - Molecules JT - Molecules (Basel, Switzerland) JID - 100964009 RN - 0 (Quaternary Ammonium Compounds) RN - 0 (Solvents) RN - CBU2X6BBJR (tetrabutylammonium) SB - IM MH - Quaternary Ammonium Compounds/*chemistry MH - Solvents/*chemistry MH - Viscosity PMC - PMC6271599 COIS- The authors declare no conflict of interest. EDAT- 2014/06/17 06:00 MHDA- 2015/01/13 06:00 PMCR- 2014/06/13 CRDT- 2014/06/17 06:00 PHST- 2014/02/12 00:00 [received] PHST- 2014/05/26 00:00 [revised] PHST- 2014/06/05 00:00 [accepted] PHST- 2014/06/17 06:00 [entrez] PHST- 2014/06/17 06:00 [pubmed] PHST- 2015/01/13 06:00 [medline] PHST- 2014/06/13 00:00 [pmc-release] AID - molecules19068011 [pii] AID - molecules-19-08011 [pii] AID - 10.3390/molecules19068011 [doi] PST - epublish SO - Molecules. 2014 Jun 13;19(6):8011-26. doi: 10.3390/molecules19068011.