PMID- 24956406 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20150511 LR - 20140711 IS - 2040-3372 (Electronic) IS - 2040-3364 (Linking) VI - 6 IP - 15 DP - 2014 Aug 7 TI - Selective removal of metallic single-walled carbon nanotubes in full length by organic film-assisted electrical breakdown. PG - 8831-5 LID - 10.1039/c4nr01690d [doi] AB - An organic film-assisted electrical breakdown technique is proposed to selectively remove metallic (m-) single-walled carbon nanotubes (SWNTs) in full length towards creation of pure semiconducting SWNT arrays which are available for the large-scale fabrication of field effect transistors (FETs). The electrical breakdown of horizontally aligned SWNT arrays embedded in organic films resulted in a maximum removal length of 16.4 mum. The removal of SWNTs was confirmed using scanning electron microscopy and Raman mapping measurements. The on/off ratios of FETs were improved up to ca. 10,000, similar to that achieved for in-air breakdown. The experimental results suggest that exothermic oxidation of organic films induces propagation of oxidation reaction, hence the long-length removal of m-SWNTs. FAU - Otsuka, Keigo AU - Otsuka K AD - Department of Mechanical Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. maruyama@photon.t.u-tokyo.ac.jp chiashi@photon.t.u-tokyo.ac.jp. FAU - Inoue, Taiki AU - Inoue T FAU - Chiashi, Shohei AU - Chiashi S FAU - Maruyama, Shigeo AU - Maruyama S LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Nanoscale JT - Nanoscale JID - 101525249 EDAT- 2014/06/24 06:00 MHDA- 2014/06/24 06:01 CRDT- 2014/06/24 06:00 PHST- 2014/06/24 06:00 [entrez] PHST- 2014/06/24 06:00 [pubmed] PHST- 2014/06/24 06:01 [medline] AID - 10.1039/c4nr01690d [doi] PST - ppublish SO - Nanoscale. 2014 Aug 7;6(15):8831-5. doi: 10.1039/c4nr01690d.