PMID- 24974140 OWN - NLM STAT- MEDLINE DCOM- 20150622 LR - 20221207 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 118 DP - 2015 Jan TI - Overview of the PCDD/Fs degradation potential and formation risk in the application of advanced oxidation processes (AOPs) to wastewater treatment. PG - 44-56 LID - S0045-6535(14)00723-1 [pii] LID - 10.1016/j.chemosphere.2014.05.077 [doi] AB - Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) are a family of unintentionally produced persistent organic pollutants (POPs) that have received considerable public and scientific attention due to the toxicity of some of their congeners, more specifically those with chlorine substitution in the 2,3,7,8 positions. The environmental management and control of PCDD/Fs is addressed at a global level through the Stockholm Convention that establishes that POPs should be destroyed or irreversibly transformed in order to reduce or eliminate their release to the environment. Several technologies, including advanced oxidation processes (AOPs) such as photolysis, photocatalysis and Fenton oxidation, have been considered as effective methods for destroying PCDD/Fs in polluted waters. Nevertheless, during the remediation of wastewaters it is critical that the treatment technologies applied do not lead to the formation of by-products that are themselves POPs, especially if PCDD/Fs precursors or chlorine are present in the reaction medium. Despite the high effectiveness of AOPs in the oxidation of major contaminants, scarce references deal with the monitoring of PCDD/Fs in the course of the oxidation process, revealing that a detailed assessment of non-combustion technologies with respect to PCDD/Fs formation is still lacking. This study reports a review of the state of the art related to the potential remediation and/or formation of PCDD/Fs as a result of the application of AOPs for the treatment of polluted waters, warning on the correct selection of the operating conditions. CI - Copyright (c) 2014 Elsevier Ltd. All rights reserved. FAU - Vallejo, Marta AU - Vallejo M AD - Departamento de Ingenierias Quimica y Biomolecular, ETSIIyT, Universidad de Cantabria, Avda. de los Castros, 39005 Santander, Spain. FAU - Fresnedo San Roman, M AU - Fresnedo San Roman M AD - Departamento de Ingenierias Quimica y Biomolecular, ETSIIyT, Universidad de Cantabria, Avda. de los Castros, 39005 Santander, Spain. FAU - Ortiz, Inmaculada AU - Ortiz I AD - Departamento de Ingenierias Quimica y Biomolecular, ETSIIyT, Universidad de Cantabria, Avda. de los Castros, 39005 Santander, Spain. Electronic address: ortizi@unican.es. FAU - Irabien, Angel AU - Irabien A AD - Departamento de Ingenierias Quimica y Biomolecular, ETSIIyT, Universidad de Cantabria, Avda. de los Castros, 39005 Santander, Spain. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Review DEP - 20140627 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Benzofurans) RN - 0 (Dioxins) RN - 0 (Waste Water) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Benzofurans/*chemistry MH - Dioxins/*chemistry MH - Oxidation-Reduction MH - *Waste Disposal, Fluid MH - Wastewater/*chemistry MH - Water Pollutants, Chemical/*chemistry OTO - NOTNLM OT - Advanced oxidation processes (AOPs) OT - Chlorinated organic compounds OT - PCDD/Fs degradation OT - PCDD/Fs formation EDAT- 2014/06/30 06:00 MHDA- 2015/06/24 06:00 CRDT- 2014/06/30 06:00 PHST- 2014/04/08 00:00 [received] PHST- 2014/05/23 00:00 [revised] PHST- 2014/05/26 00:00 [accepted] PHST- 2014/06/30 06:00 [entrez] PHST- 2014/06/30 06:00 [pubmed] PHST- 2015/06/24 06:00 [medline] AID - S0045-6535(14)00723-1 [pii] AID - 10.1016/j.chemosphere.2014.05.077 [doi] PST - ppublish SO - Chemosphere. 2015 Jan;118:44-56. doi: 10.1016/j.chemosphere.2014.05.077. Epub 2014 Jun 27.