PMID- 25001335
OWN - NLM
STAT- MEDLINE
DCOM- 20140926
LR  - 20161125
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1356
DP  - 2014 Aug 22
TI  - Sorptive extraction using polydimethylsiloxane/metal-organic framework coated 
      stir bars coupled with high performance liquid chromatography-fluorescence 
      detection for the determination of polycyclic aromatic hydrocarbons in 
      environmental water samples.
PG  - 45-53
LID - S0021-9673(14)00988-1 [pii]
LID - 10.1016/j.chroma.2014.06.062 [doi]
AB  - In this work, metal-organic frameworks (MOFs, Al-MIL-53-NH(2)) were synthesized via 
      the hydrothermal method, and novel polydimethylsiloxane/metal-organic framework 
      (PDMS/MOFs, PDMS/Al-MIL-53-NH(2))-coated stir bars were prepared by the sol-gel 
      technique. The preparation reproducibility of the PDMS/MOFs-coated stir bar was 
      good, with relative standard deviations (RSDs) ranging from 4.8% to 14.9% (n=7) 
      within one batch and from 6.2% to 16.9% (n=6) among different batches. Based on 
      this fact, a new method of PDMS/MOFs-coated stir bar sorptive extraction (SBSE) 
      and ultrasonic-assisted liquid desorption (UALD) coupled with high performance 
      liquid chromatography-fluorescence detection (HPLC-FLD) was developed for the 
      determination of polycyclic aromatic hydrocarbons (PAHs) in environmental water 
      samples. To obtain the best extraction performance for PAHs, several parameters 
      affecting SBSE, such as extraction time, stirring rate, and extraction 
      temperature, were investigated. Under optimal experimental conditions, wide 
      linear ranges and good RSDs (n=7) were obtained. With enrichment factors (EFs) of 
      16.1- to 88.9-fold (theoretical EF, 142-fold), the limits of detection (LODs, 
      S/N=3) of the developed method for the target PAHs were found to be in the range 
      of 0.05-2.94 ng/L. The developed method was successfully applied to the analysis 
      of PAHs in Yangtze River and East Lake water samples.
CI  - Copyright (c) 2014 Elsevier B.V. All rights reserved.
FAU - Hu, Cong
AU  - Hu C
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of 
      Education, Department of Chemistry, Wuhan University, Wuhan 430072, China.
FAU - He, Man
AU  - He M
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of 
      Education, Department of Chemistry, Wuhan University, Wuhan 430072, China.
FAU - Chen, Beibei
AU  - Chen B
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of 
      Education, Department of Chemistry, Wuhan University, Wuhan 430072, China.
FAU - Zhong, Cheng
AU  - Zhong C
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of 
      Education, Department of Chemistry, Wuhan University, Wuhan 430072, China.
FAU - Hu, Bin
AU  - Hu B
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of 
      Education, Department of Chemistry, Wuhan University, Wuhan 430072, China. 
      Electronic address: binhu@whu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140624
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Coordination Complexes)
RN  - 0 (Dimethylpolysiloxanes)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Water Pollutants, Chemical)
RN  - 63148-62-9 (baysilon)
RN  - CPD4NFA903 (Aluminum)
SB  - IM
MH  - Adsorption
MH  - Aluminum/*chemistry
MH  - China
MH  - Chromatography, High Pressure Liquid
MH  - Coordination Complexes/chemistry
MH  - Dimethylpolysiloxanes/*chemistry
MH  - Fluorometry
MH  - Hydrogen-Ion Concentration
MH  - Lakes
MH  - Limit of Detection
MH  - Liquid-Liquid Extraction/instrumentation
MH  - Polycyclic Aromatic Hydrocarbons/analysis/*isolation & purification
MH  - Reproducibility of Results
MH  - Rivers
MH  - Signal-To-Noise Ratio
MH  - Sound
MH  - Water Pollutants, Chemical/analysis/*isolation & purification
OTO - NOTNLM
OT  - Environmental water samples
OT  - High performance liquid chromatography-fluorescence detection
OT  - Metal-organic frameworks (MOFs, Al-MIL-53-NH(2))
OT  - Polycyclic aromatic hydrocarbons
OT  - Stir bar sorptive extraction
EDAT- 2014/07/09 06:00
MHDA- 2014/09/27 06:00
CRDT- 2014/07/09 06:00
PHST- 2014/04/08 00:00 [received]
PHST- 2014/06/19 00:00 [revised]
PHST- 2014/06/19 00:00 [accepted]
PHST- 2014/07/09 06:00 [entrez]
PHST- 2014/07/09 06:00 [pubmed]
PHST- 2014/09/27 06:00 [medline]
AID - S0021-9673(14)00988-1 [pii]
AID - 10.1016/j.chroma.2014.06.062 [doi]
PST - ppublish
SO  - J Chromatogr A. 2014 Aug 22;1356:45-53. doi: 10.1016/j.chroma.2014.06.062. Epub 
      2014 Jun 24.