PMID- 25113217 OWN - NLM STAT- MEDLINE DCOM- 20141028 LR - 20140812 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 114 DP - 2014 Nov TI - Sorption behaviors of a persistent toxaphene congener on marine sediments under different physicochemical conditions. PG - 310-6 LID - S0045-6535(14)00640-7 [pii] LID - 10.1016/j.chemosphere.2014.05.016 [doi] AB - Sorptive processes are important parameters affecting the mobility, availability and fate of persistent organic pollutants (POPs), such as toxaphene, in aquatic systems. The sorption and desorption behaviors of the B7-1450, a stable toxaphene congener in environment, on marine sediment was studied under different temperature and salinity conditions to better understand the B-1450 distribution in estuarine systems. The data were fitted to different sorption models to characterize sorption behaviors by evaluating sorption coefficients and sequestrated fraction of B7-1450 on sediments. High carbon-normalized sorption coefficients (Koc) of the B7-1450 were observed with values ranging from 3.2x104 to 6.0x104 mL g(-1) under experimental conditions. The data showed an increase of B7-1450 sorption coefficients with the salinity and a decrease with temperature. These investigations indicate that B7-1450 is three times more sequestred on sediments in cold (2 degrees C, 30 psu) than in warm marine conditions (20 degrees C, 30 psu). These results suggest that the mobility and bioavailable of B7-1450 or other POPs from the sediments could be less important in cold marine comparatively in warm marine and warm freshwater media. As a result of climate changes, the warming of mid and high latitudes coastal waters could enhance the mobility of POPs. CI - Copyright (c) 2014 Elsevier Ltd. All rights reserved. FAU - Soubaneh, Youssouf Djibril AU - Soubaneh YD AD - Institut des sciences de la mer de Rimouski, Universite du Quebec a Rimouski, 310, Allee des Ursulines, Rimouski, QC G5L 3A1, Canada. Electronic address: Youssoufdjibril_Soubaneh@uqar.ca. FAU - Gagne, Jean-Pierre AU - Gagne JP AD - Institut des sciences de la mer de Rimouski, Universite du Quebec a Rimouski, 310, Allee des Ursulines, Rimouski, QC G5L 3A1, Canada. FAU - Lebeuf, Michel AU - Lebeuf M AD - Department of Fisheries and Oceans, Maurice Lamontagne Institute, P.O. Box 1000, 850 Route de la Mer, Mont-Joli, QC G5H 3Z4, Canada. FAU - Gouteux, Bruno AU - Gouteux B AD - Aquatic Ecosystem Protection Research Division, Environment Canada, Burlington, ON L7R 4A6, Canada. FAU - Nikiforov, Vladimir AU - Nikiforov V AD - Saint-Petersburg Scientific Research Centre for Ecological Safety, Russian Academy of Sciences, Korpusnaya, 18, St. Petersburg 197110, Russia. FAU - Awaleh, Mohamed Osman AU - Awaleh MO AD - Laboratoire de Chimie, Institut des Sciences de la Terre, Centre d'Etude et de Recherche de Djibouti (CERD), Route de l'aeroport, B.P. 486, Republic of Djibouti. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20140602 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Insecticides) RN - 0 (Water Pollutants, Chemical) RN - 7440-44-0 (Carbon) RN - 8001-35-2 (Toxaphene) SB - IM MH - Adsorption MH - Carbon/chemistry MH - Geologic Sediments/*analysis MH - Insecticides/*isolation & purification MH - Salinity MH - Temperature MH - Toxaphene/*isolation & purification MH - Water Pollutants, Chemical/*isolation & purification OTO - NOTNLM OT - Desorption-sequestration OT - Estuarine sediment OT - POPs OT - Salting out OT - Sorption coefficient OT - Temperature effect EDAT- 2014/08/13 06:00 MHDA- 2014/10/29 06:00 CRDT- 2014/08/13 06:00 PHST- 2013/09/12 00:00 [received] PHST- 2014/05/05 00:00 [revised] PHST- 2014/05/06 00:00 [accepted] PHST- 2014/08/13 06:00 [entrez] PHST- 2014/08/13 06:00 [pubmed] PHST- 2014/10/29 06:00 [medline] AID - S0045-6535(14)00640-7 [pii] AID - 10.1016/j.chemosphere.2014.05.016 [doi] PST - ppublish SO - Chemosphere. 2014 Nov;114:310-6. doi: 10.1016/j.chemosphere.2014.05.016. Epub 2014 Jun 2.