PMID- 25160956
OWN - NLM
STAT- MEDLINE
DCOM- 20150304
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1362
DP  - 2014 Oct 3
TI  - Amine-functional magnetic polymer modified graphene oxide as magnetic solid-phase 
      extraction materials combined with liquid chromatography-tandem mass spectrometry 
      for chlorophenols analysis in environmental water.
PG  - 34-42
LID - S0021-9673(14)01257-6 [pii]
LID - 10.1016/j.chroma.2014.08.027 [doi]
AB  - A novel planar-structure amine-functional magnetic polymer modified graphene 
      oxide nanocomposite (NH2-MP@GO) was synthesized. The properties were 
      characterized by transmission electron microscopy (TEM) and Fourier-transform 
      infrared spectrometry (FTIR). The obtained adsorption results showed that the 
      NH2-MP@GO had great adsorptive ability toward five chlorophenols (CPs), including 
      2-chlorophenol (2-CP), 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol 
      (2,4,6-TCP), 2,3,4,6-tetrachlorophenol (2,3,4,6-TeCP) and pentachlorophenol 
      (PCP). Based on these, an effective magnetic solid-phase extraction (MSPE) 
      procedure coupled with high-performance liquid chromatography-tandem mass 
      spectrometry (LC-MS/MS) for the preconcentration and determination of the five 
      CPs in environmental water samples was developed. Various experimental parameters 
      that could affect the extraction efficiencies had been investigated in detail. 
      Under the optimum conditions, the enrichment factors of the method for the target 
      CPs were found to be 1000. The proposed method was successfully applied for the 
      analysis of environmental water samples with recoveries ranging from 86.4 to 
      99.8% with correlation coefficients (R) higher than 0.9994. Good linearities were 
      obtained ranging from 10 to 500ng/L for 2-CP, 5 to 500ng/L for 2,4-DCP, 2 to 
      500ng/L for 2,4,6-TeCP and 2,3,4,6-TeCP, and 1 to 500ng/L for PCP, respectively. 
      The limits of quantitation for the five CPs were 0.6-9.2ng/L. It was confirmed 
      that the planar-structure NH2-MP@GO was a kind of highly effective MSPE materials 
      used for the trace CPs analyses.
CI  - Copyright (c) 2014 Elsevier B.V. All rights reserved.
FAU - Pan, Sheng-Dong
AU  - Pan SD
AD  - Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic 
      Chemicals, Ningbo Municipal Center for Disease Control and Prevention, Ningbo, 
      Zhejiang 315010, China; Ningbo Key Laboratory of Poison Research and Control, 
      Ningbo Municipal Center for Disease Control and Prevention, Ningbo 315010, China.
FAU - Zhou, Li-Xin
AU  - Zhou LX
AD  - Medical School, Ningbo University, Ningbo, Zhejiang 315211, China.
FAU - Zhao, Yong-Gang
AU  - Zhao YG
AD  - Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic 
      Chemicals, Ningbo Municipal Center for Disease Control and Prevention, Ningbo, 
      Zhejiang 315010, China; Ningbo Key Laboratory of Poison Research and Control, 
      Ningbo Municipal Center for Disease Control and Prevention, Ningbo 315010, China.
FAU - Chen, Xiao-Hong
AU  - Chen XH
AD  - Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic 
      Chemicals, Ningbo Municipal Center for Disease Control and Prevention, Ningbo, 
      Zhejiang 315010, China; Ningbo Key Laboratory of Poison Research and Control, 
      Ningbo Municipal Center for Disease Control and Prevention, Ningbo 315010, China.
FAU - Shen, Hao-Yu
AU  - Shen HY
AD  - Ningbo Institute of Technology, Zhejiang University, Ningbo, Zhejiang 315100, 
      China.
FAU - Cai, Mei-Qiang
AU  - Cai MQ
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou 310018, China.
FAU - Jin, Mi-Cong
AU  - Jin MC
AD  - Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic 
      Chemicals, Ningbo Municipal Center for Disease Control and Prevention, Ningbo, 
      Zhejiang 315010, China; Ningbo Key Laboratory of Poison Research and Control, 
      Ningbo Municipal Center for Disease Control and Prevention, Ningbo 315010, China. 
      Electronic address: jmcjc@163.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140815
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Amines)
RN  - 0 (Chlorophenols)
RN  - 0 (Oxides)
RN  - 0 (Polymers)
RN  - 059QF0KO0R (Water)
RN  - 7782-42-5 (Graphite)
SB  - IM
MH  - Adsorption
MH  - Amines/*chemistry
MH  - Chlorophenols/*analysis
MH  - Chromatography, Liquid/instrumentation/*methods
MH  - Graphite/chemistry
MH  - Hydrogen-Ion Concentration
MH  - Limit of Detection
MH  - Magnetic Phenomena
MH  - Oxides/*chemistry
MH  - Polymers/chemistry
MH  - Solid Phase Extraction/instrumentation/*methods
MH  - Tandem Mass Spectrometry/instrumentation/*methods
MH  - Water/*chemistry
OTO - NOTNLM
OT  - Amine-functional magnetic graphene
OT  - Chlorophenol
OT  - Environmental water
OT  - LC-MS/MS
OT  - Magnetic solid-phase extraction
EDAT- 2014/08/28 06:00
MHDA- 2015/03/05 06:00
CRDT- 2014/08/28 06:00
PHST- 2014/05/21 00:00 [received]
PHST- 2014/08/05 00:00 [revised]
PHST- 2014/08/07 00:00 [accepted]
PHST- 2014/08/28 06:00 [entrez]
PHST- 2014/08/28 06:00 [pubmed]
PHST- 2015/03/05 06:00 [medline]
AID - S0021-9673(14)01257-6 [pii]
AID - 10.1016/j.chroma.2014.08.027 [doi]
PST - ppublish
SO  - J Chromatogr A. 2014 Oct 3;1362:34-42. doi: 10.1016/j.chroma.2014.08.027. Epub 
      2014 Aug 15.