PMID- 25185310
OWN - NLM
STAT- MEDLINE
DCOM- 20150901
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 32
IP  - 5
DP  - 2014 May
TI  - [Determination of N-methyl carbamate pesticides in diet samples by high 
      performance liquid chromatography-linear ion trap mass spectrometry with gel 
      permeation chromatography cleanup].
PG  - 499-505
AB  - A method for the determination of N-methyl carbamate (NMC) pesticides in diet 
      samples was developed by high performance liquid chromatography-linear ion trap 
      mass spectrometry (HPLC-LIT-MS). The samples with the isotope internal standard 
      were ultrasonically extracted with acetonitrile saturated with cyclohexane, and 
      then cleaned-up by passing through gel permeation chromatographic (GPC) column. 
      The LC separation was performed on a CAPCELL PAK CR column (100 mm x 2.1 mm, 5 
      microm; SCX-C18 (1 : 4)) using acetonitrile and 5 mmol/L ammonium formate/0.1% 
      (v/v) formic acid aqueous solution as mobile phases (gradient elution) at a flow 
      rate of 0.2 mL/min. The ionization of the analytes was performed by positive 
      electrospray mode. Selective reaction monitoring (SRM) was used for the 
      monitoring of MS3 transitions for each compound. The internal standard was used 
      for quantitation. The average recoveries were in the range of 60.4% - 114%, and 
      the relative standard deviations (RSDs) were all not more than 16.2%. The limits 
      of detection (LODs) were 0.001-0.010 mg/kg. The method was successfully applied 
      to the determination of 15 compounds of interest in nine foodstuffs from the 
      fourth Chinese Total Diet Study (TDS) performed in 2007, and aldicarb and 
      carbofuran were found in several samples.
FAU - Yang, Xin
AU  - Yang X
FAU - Li, Peng
AU  - Li P
FAU - Miao, Hong
AU  - Miao H
FAU - Zhao, Yunfeng
AU  - Zhao Y
FAU - Wu, Yongning
AU  - Wu Y
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Carbamates)
RN  - 0 (Pesticide Residues)
RN  - 8V071SH05P (Aldicarb)
RN  - 9WFX634X2T (methyl carbamate)
RN  - SKF77S6Y67 (Carbofuran)
SB  - IM
MH  - Aldicarb
MH  - Carbamates/*analysis
MH  - Carbofuran
MH  - Chromatography, Gel
MH  - Chromatography, High Pressure Liquid
MH  - Food Contamination/*analysis
MH  - Limit of Detection
MH  - Mass Spectrometry
MH  - Pesticide Residues/*analysis
EDAT- 2014/09/05 06:00
MHDA- 2015/09/02 06:00
CRDT- 2014/09/05 06:00
PHST- 2014/09/05 06:00 [entrez]
PHST- 2014/09/05 06:00 [pubmed]
PHST- 2015/09/02 06:00 [medline]
AID - 10.3724/sp.j.1123.2013.12041 [doi]
PST - ppublish
SO  - Se Pu. 2014 May;32(5):499-505. doi: 10.3724/sp.j.1123.2013.12041.