PMID- 25220452
OWN - NLM
STAT- MEDLINE
DCOM- 20150721
LR  - 20211021
IS  - 1573-4994 (Electronic)
IS  - 1053-0509 (Linking)
VI  - 24
IP  - 6
DP  - 2014 Nov
TI  - A highly selective turn-on fluorescent chemodosimeter for Cu(2+) through a Cu 
      (2+)-promoted redox reaction.
PG  - 1671-7
LID - 10.1007/s10895-014-1454-4 [doi]
AB  - A highly sensitive and selective photoinduced electron transfer (PET) 
      fluorescence chemodosimeter L for Cu(2+) detection has been synthesized and 
      characterized. This PET chemosensor composed of a butano-tethered electron-riched 
      phenothiazine (Ptz) donor and acridine orange (AO) signalling element. Based on 
      the Cu(2+)-promoted oxidation of Ptz donor, the signalling element AO showed a 
      unique fluorescent turn-on properties, which led to a highly Cu(2+)-specific 
      fluorescent chemodosimeter. A fluorescent enhancement factor over 8-fold can be 
      reached by fully blocking the PET channel with a detection limit down to the 
      10(-7) M range. Meanwhile, the reversibility of the chemodosimeter L can be 
      realized by the addition of L-cysteine.
FAU - Liang, Lijuan
AU  - Liang L
AD  - School of Materials Science & Engineering, Institute of Information Functional 
      Materials& Devices, Harbin Institute of Technology, Harbin, 150001, China.
FAU - Zhao, Liancheng
AU  - Zhao L
FAU - Zeng, Xianshun
AU  - Zeng X
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140916
PL  - Netherlands
TA  - J Fluoresc
JT  - Journal of fluorescence
JID - 9201341
RN  - 0 (Coloring Agents)
RN  - 0 (Fluorescent Dyes)
RN  - 0 (Phenothiazines)
RN  - 789U1901C5 (Copper)
RN  - F30N4O6XVV (Acridine Orange)
RN  - GS9EX7QNU6 (phenothiazine)
SB  - IM
MH  - Acridine Orange/*chemistry
MH  - Biosensing Techniques
MH  - Coloring Agents/*chemistry
MH  - Copper/*chemistry
MH  - Electron Transport
MH  - *Electrons
MH  - Fluorescent Dyes/*chemistry
MH  - *Light
MH  - Limit of Detection
MH  - Molecular Structure
MH  - Oxidation-Reduction
MH  - Phenothiazines/*chemistry
MH  - Spectrometry, Fluorescence
EDAT- 2014/09/16 06:00
MHDA- 2015/07/22 06:00
CRDT- 2014/09/16 06:00
PHST- 2014/07/23 00:00 [received]
PHST- 2014/09/04 00:00 [accepted]
PHST- 2014/09/16 06:00 [entrez]
PHST- 2014/09/16 06:00 [pubmed]
PHST- 2015/07/22 06:00 [medline]
AID - 10.1007/s10895-014-1454-4 [doi]
PST - ppublish
SO  - J Fluoresc. 2014 Nov;24(6):1671-7. doi: 10.1007/s10895-014-1454-4. Epub 2014 Sep 
      16.