PMID- 25255564
OWN - NLM
STAT- MEDLINE
DCOM- 20150901
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 32
IP  - 7
DP  - 2014 Jul
TI  - [Simultaneous determination of six perfluorinated organic compounds in feed by 
      using polyamide solid-phase extraction with ultra performance liquid 
      chromatography-tandem mass spectrometry].
PG  - 723-9
AB  - A method for the determination of six perfluorinated organic compounds (PFCs) in 
      feed has been developed. It is based on polyamide solid-phase extraction (SPE) 
      together with ultra performance liquid chromatography-tandem mass spectrometry 
      (UPLC-MS/MS). The sample was extracted by acidified acetonitrile. The extraction 
      solution was enriched by a polyamide SPE cartridge under acidic condition, and 
      cleaned-up using methanol, eluted by 5% (v/v) ammonia/methanol solvent and 
      determined by UPLC-MS/MS. The UPLC separation was carried out on an Acquity BEH 
      C18 column (100 mm x 2.1 mm, 1.7 microm). The mobile phases were 5 mmol/L 
      ammonium acetate and acetonitrile with a gradient elution. Under the optimal 
      conditions, the PFCs were analyzed under multiple reaction monitoring (MRM) mode 
      with negative electrospray ionization. The isotope internal standard method was 
      used to determine the six PFCs, and improve the quantitative accuracy. All of the 
      target compounds exhibited good linearity (r > 0.995) over a concentration range 
      of 0.5-25 microg/L. The detection limits of the six PFCs were all smaller than 
      0.1 microg/kg. The mean recoveries of the six PFCs were in the range of 94.2% to 
      108.9% with the relative standard deviations (RSDs) of 1.8% - 8.6% (n = 6). The 
      method for the determination of PFCs in feed is low-cost, favorable effect and 
      suitable for the detection of complex matrix samples.
FAU - Lin, Qin
AU  - Lin Q
FAU - Fu, Fengfu
AU  - Fu F
FAU - Chen, Guonan
AU  - Chen G
FAU - Zheng, Xiaoyan
AU  - Zheng X
FAU - Dai, Ming
AU  - Dai M
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Organic Chemicals)
SB  - IM
MH  - Animal Feed/*analysis
MH  - Chromatography, High Pressure Liquid
MH  - Organic Chemicals/*analysis
MH  - Solid Phase Extraction
MH  - *Tandem Mass Spectrometry
EDAT- 2014/09/27 06:00
MHDA- 2015/09/02 06:00
CRDT- 2014/09/27 06:00
PHST- 2014/09/27 06:00 [entrez]
PHST- 2014/09/27 06:00 [pubmed]
PHST- 2015/09/02 06:00 [medline]
AID - 10.3724/sp.j.1123.2014.03023 [doi]
PST - ppublish
SO  - Se Pu. 2014 Jul;32(7):723-9. doi: 10.3724/sp.j.1123.2014.03023.