PMID- 25255566
OWN - NLM
STAT- MEDLINE
DCOM- 20150901
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 32
IP  - 7
DP  - 2014 Jul
TI  - [Determination of six phthalate acid esters in camellia oil by gas 
      chromatography-mass spectrometry coupled with solid-phase extraction using 
      single-walled carbon nanotubes as adsorbent].
PG  - 735-40
AB  - An analytical method based on solid-phase extraction with single-walled carbon 
      nanotubes (SWCNTs) as adsorbent was developed for the simultaneous determination 
      of six phthalate acid esters (PAEs) in camellia oil by gas chromatography-mass 
      spectrometry (GC-MS). The samples were diluted by hexane and then cleaned up with 
      a glass SWCNTs solid phase extraction (SPE) column. The PAEs were measured by 
      GC-MS in selected ion monitoring (SIM) mode, using external standard method for 
      quantitative analysis. The important factors affecting extraction efficiency, 
      such as the dilution volume of hexane, the type of adsorbent material, the dosage 
      of SWCNTs, the volume of wash solution, the type and volume of elution solution 
      were optimized. The optimal conditions were as follows: the dilution volume of 
      hexane was 5 mL, the dosage of SWCNTs was 0.6 g, the wash solution was 20 mL 
      hexane, and the elution solution was 5 mL toluene. The six PAEs had a good linear 
      range from 0.05 mg/L to 1.0 mg/L, with the correlation coefficients (r) all above 
      0.999 9. The average recoveries of the six targets in spiked camellia oil (from 
      0.05 mg/kg to 1.0 mg/kg) ranged from 86.4% to 111.7% with the relative standard 
      deviations (RSDs) from 4.2% to 10.4%. The developed method is accurate, quick and 
      suitable for the determination of the six PAEs in camellia oil.
FAU - Zhang, Fan
AU  - Zhang F
FAU - Li, Zhonghai
AU  - Li Z
FAU - Zhang, Ying
AU  - Zhang Y
FAU - Huang, Zhiqiang
AU  - Huang Z
FAU - Wang, Xiaosong
AU  - Wang X
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Esters)
RN  - 0 (Nanotubes, Carbon)
RN  - 0 (Phthalic Acids)
RN  - 0 (Plant Oils)
RN  - 6O7F7IX66E (phthalic acid)
SB  - IM
MH  - *Camellia
MH  - Esters/*analysis
MH  - Gas Chromatography-Mass Spectrometry
MH  - Nanotubes, Carbon
MH  - Phthalic Acids/*analysis
MH  - Plant Oils/*chemistry
MH  - Solid Phase Extraction
EDAT- 2014/09/27 06:00
MHDA- 2015/09/02 06:00
CRDT- 2014/09/27 06:00
PHST- 2014/09/27 06:00 [entrez]
PHST- 2014/09/27 06:00 [pubmed]
PHST- 2015/09/02 06:00 [medline]
AID - 10.3724/sp.j.1123.2014.04036 [doi]
PST - ppublish
SO  - Se Pu. 2014 Jul;32(7):735-40. doi: 10.3724/sp.j.1123.2014.04036.