PMID- 25256521
OWN - NLM
STAT- MEDLINE
DCOM- 20151013
LR  - 20140926
IS  - 1879-1344 (Electronic)
IS  - 0144-8617 (Linking)
VI  - 113
DP  - 2014 Nov 26
TI  - 2,6-Dinitroaniline and beta-cyclodextrin inclusion complex properties studied by 
      different analytical methods.
PG  - 577-87
LID - S0144-8617(14)00747-4 [pii]
LID - 10.1016/j.carbpol.2014.07.062 [doi]
AB  - The formation of supramolecular host-guest inclusion complex of 
      2,6-Dinitroaniline (2,6-DNA) with nano-hydrophobic cavity of beta-cyclodextrin 
      (beta-CD) in solution phase were studied by UV-visible spectrophotometer and 
      electrochemical method (cyclic voltammetry, CV). The prototropic behaviors of 
      2,6-DNA with and without beta-CD and the ground state acidity constant (pKa) of 
      host-guest inclusion complex (2,6-DNA-beta-CD) was studied by 
      Spectrophotometrically. The binding constant of inclusion complex at 303 K was 
      calculated using Benesi-Hildebrand plot and thermodynamic parameter (DeltaG) were 
      also calculated. The solid inclusion complex formation between beta-CD and 2,6-DNA 
      was confirmed by (1)H NMR, FT-IR, XRD and SEM analysis. The beta-CD:2,6-DNA 
      inclusion complex obtained by molecular docking studies is in good correlation 
      with the results obtained through experimental methods.
CI  - Copyright (c) 2014 Elsevier Ltd. All rights reserved.
FAU - Srinivasan, Krishnan
AU  - Srinivasan K
AD  - Department of Industrial Chemistry, School of Chemical Sciences, Alagappa 
      University, Karaikudi 630 003, Tamilnadu, India.
FAU - Sivakumar, Krishnamoorthy
AU  - Sivakumar K
AD  - Department of Chemistry, Sri Chandrasekharendra Saraswathi Viswa Mahavidyalaya 
      University, Enathur, Kanchipuram 631 561, Tamilnadu, India.
FAU - Stalin, Thambusamy
AU  - Stalin T
AD  - Department of Industrial Chemistry, School of Chemical Sciences, Alagappa 
      University, Karaikudi 630 003, Tamilnadu, India. Electronic address: 
      drstalin76@gmail.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20140812
PL  - England
TA  - Carbohydr Polym
JT  - Carbohydrate polymers
JID - 8307156
RN  - 0 (Aniline Compounds)
RN  - 0 (Solutions)
RN  - 0 (beta-Cyclodextrins)
RN  - JV039JZZ3A (betadex)
SB  - IM
MH  - Aniline Compounds/*chemistry
MH  - Electrochemical Techniques
MH  - Magnetic Resonance Spectroscopy
MH  - Solutions/*chemistry
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Thermodynamics
MH  - X-Ray Diffraction
MH  - beta-Cyclodextrins/*chemistry
OTO - NOTNLM
OT  - 2,6-Dinitroaniline
OT  - Inclusion complex
OT  - Patch dock server
OT  - beta-Cyclodextrin
EDAT- 2014/09/27 06:00
MHDA- 2015/10/16 06:00
CRDT- 2014/09/27 06:00
PHST- 2013/12/09 00:00 [received]
PHST- 2014/06/27 00:00 [revised]
PHST- 2014/07/20 00:00 [accepted]
PHST- 2014/09/27 06:00 [entrez]
PHST- 2014/09/27 06:00 [pubmed]
PHST- 2015/10/16 06:00 [medline]
AID - S0144-8617(14)00747-4 [pii]
AID - 10.1016/j.carbpol.2014.07.062 [doi]
PST - ppublish
SO  - Carbohydr Polym. 2014 Nov 26;113:577-87. doi: 10.1016/j.carbpol.2014.07.062. Epub 
      2014 Aug 12.