PMID- 25310710
OWN - NLM
STAT- MEDLINE
DCOM- 20150608
LR  - 20231213
IS  - 1520-5118 (Electronic)
IS  - 0021-8561 (Linking)
VI  - 62
IP  - 42
DP  - 2014 Oct 22
TI  - Chlorpyrifos residual behaviors in field crops and transfers during duck pellet 
      feed processing.
PG  - 10215-21
LID - 10.1021/jf502192c [doi]
AB  - Chlorpyrifos is a widely used organophosphorus pesticide in agricultural crops 
      (including food) and animal feeds in China, resulting in heavy contamination. 
      Many studies have focused on the food-processing effects on chlorpyrifos removal, 
      but sufficient information is not observed for feed-processing steps. Here, 
      chlorpyrifos residual behaviors in field crops and its transfers in duck pellet 
      feed-processing steps were evaluated. In field trials, the highest residues for 
      rice grain, shelled corn, and soybean seed were 12.0, 0.605, and 0.220 mg/kg, 
      respectively. Residues of all rice grain and about half of shelled corn exceeded 
      the maximum residue limits (MRLs) of China, and five soybean seeds exceeded the 
      MRL of China. Chlorpyrifos residue was reduced 38.2% in brown rice after the raw 
      rice grain was hulled. The residue in bran increased 71.2% after milling from 
      brown rice. During the squashing step, the residue reduced 73.8% in soybean meal. 
      The residues reduced significantly (23.7-36.8%) during the process of granulating 
      for rice, maize, and soybean products. Comparatively, the grinding process showed 
      only limited influence on chlorpyrifos removal (<10%). The residues of duck 
      pellet feeds produced from highly contaminated raw materials of this study were 
      1.01 mg/kg (maize-soybean feed) and 3.20 mg/kg (rice-soybean feed), which were 
      much higher than the generally accepted value (>0.1 mg/kg) for animal feeding. 
      Chlorpyrifos residues were removed significantly by processing steps of pellet 
      feeds, but the residue of raw materials was the determining factor for the safety 
      of duck feeding.
FAU - Li, Rui
AU  - Li R
AD  - State Key Laboratory Breeding Base for Zhejiang Sustainable Plant Pest Control, 
      Agricultural Ministry Key Laboratory for Pesticide Residue Detection, Zhejiang 
      Province Key Laboratory for Food Safety, Institute of Quality and Standard for 
      Agro-products, Zhejiang Academy of Agricultural Sciences , 310021 Hangzhou, 
      Zhejiang, China.
FAU - Wei, Wei
AU  - Wei W
FAU - He, Liang
AU  - He L
FAU - Hao, Lili
AU  - Hao L
FAU - Ji, Xiaofeng
AU  - Ji X
FAU - Zhou, Yu
AU  - Zhou Y
FAU - Wang, Qiang
AU  - Wang Q
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20141013
PL  - United States
TA  - J Agric Food Chem
JT  - Journal of agricultural and food chemistry
JID - 0374755
RN  - 0 (Pesticide Residues)
RN  - JCS58I644W (Chlorpyrifos)
SB  - IM
MH  - Animal Feed/*analysis
MH  - Animals
MH  - China
MH  - Chlorpyrifos/*analysis
MH  - Crops, Agricultural/*chemistry/metabolism
MH  - Ducks/*metabolism
MH  - Food Contamination/*analysis
MH  - Food Handling
MH  - Humans
MH  - Meat/*analysis
MH  - Oryza/chemistry/metabolism
MH  - Pesticide Residues/*analysis
MH  - Glycine max/chemistry/metabolism
MH  - Zea mays/chemistry/metabolism
OTO - NOTNLM
OT  - chlorpyrifos
OT  - feed processing
OT  - field corps
OT  - pellet feed
OT  - pesticide residue
EDAT- 2014/10/14 06:00
MHDA- 2015/06/09 06:00
CRDT- 2014/10/14 06:00
PHST- 2014/10/14 06:00 [entrez]
PHST- 2014/10/14 06:00 [pubmed]
PHST- 2015/06/09 06:00 [medline]
AID - 10.1021/jf502192c [doi]
PST - ppublish
SO  - J Agric Food Chem. 2014 Oct 22;62(42):10215-21. doi: 10.1021/jf502192c. Epub 2014 
      Oct 13.