PMID- 25361232
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20150511
LR  - 20141114
IS  - 1463-9084 (Electronic)
IS  - 1463-9076 (Linking)
VI  - 16
IP  - 47
DP  - 2014 Dec 21
TI  - Effect of cationic head group on micellization behavior of new 
      amide-functionalized surface active ionic liquids.
PG  - 26040-50
LID - 10.1039/c4cp04054f [doi]
AB  - Amide-functionalized surface active ionic liquids (SAILs), 1-methyl-1-dodecyl 
      piperidinium chloride, [C12APip][Cl]; 1-methyl-1-dodecyl pyrrolidinium chloride, 
      [C12APyrr][Cl]; 1-methyl-3-dodecyl imidazolium chloride, [C12Amim][Cl], and 
      1-methyl-1-dodecyl morpholinium chloride, [C12AMorph][Cl], have been synthesized, 
      characterized and investigated for thermal stability, and micellization behavior 
      in aqueous medium. The introduction of an amide moiety in the alkyl chain 
      decreased the thermal stability of the functionalized SAILs compared to 
      non-functionalized SAILs bearing a simple alkyl chain. A variety of state of the 
      art techniques, viz. tensiometry, conductometry, steady-state fluorescence, 
      isothermal titration calorimetry (ITC), dynamic light scattering (DLS) and atomic 
      force microscopy (AFM), have been employed to investigate the micellization 
      behavior. Amide-functionalized SAILs have shown much lower critical micelle 
      concentration, cmc, and better surface active properties as compared to 
      homologous non-functionalized SAILs. Steady-state fluorescence has provided 
      information about cmc, aggregation number (Nagg) and polarity of the cybotactic 
      region of the micelles, whereas ITC has provided insights into the thermodynamics 
      of micellization. Furthermore, the size and shape of the micelles have been 
      investigated using DLS and AFM techniques.
FAU - Kamboj, Raman
AU  - Kamboj R
AD  - Department of Chemistry, UGC-Centre for Advanced Studies-I, Guru Nanak Dev 
      University, Amritsar-143005, India. tejwantsinghkang@gmail.com 
      sukhprit@gmail.com.
FAU - Bharmoria, Pankaj
AU  - Bharmoria P
FAU - Chauhan, Vinay
AU  - Chauhan V
FAU - Singh, Gurbir
AU  - Singh G
FAU - Kumar, Arvind
AU  - Kumar A
FAU - Singh, Sukhprit
AU  - Singh S
FAU - Kang, Tejwant Singh
AU  - Kang TS
LA  - eng
PT  - Journal Article
DEP - 20141031
PL  - England
TA  - Phys Chem Chem Phys
JT  - Physical chemistry chemical physics : PCCP
JID - 100888160
EDAT- 2014/11/02 06:00
MHDA- 2014/11/02 06:01
CRDT- 2014/11/01 06:00
PHST- 2014/11/01 06:00 [entrez]
PHST- 2014/11/02 06:00 [pubmed]
PHST- 2014/11/02 06:01 [medline]
AID - 10.1039/c4cp04054f [doi]
PST - ppublish
SO  - Phys Chem Chem Phys. 2014 Dec 21;16(47):26040-50. doi: 10.1039/c4cp04054f. Epub 
      2014 Oct 31.