PMID- 25427515
OWN - NLM
STAT- MEDLINE
DCOM- 20150727
LR  - 20141127
IS  - 1873-0191 (Electronic)
IS  - 0928-4931 (Linking)
VI  - 33
IP  - 2
DP  - 2013 Mar 1
TI  - A Ho(III) potentiometric polymeric membrane sensor based on a new four dentate 
      neutral ion carrier.
PG  - 984-8
LID - S0928-4931(12)00552-8 [pii]
LID - 10.1016/j.msec.2012.11.034 [doi]
AB  - In this research, we report a new Ho(3+)-PVC membrane electrode based on 
      N-(4,5-dimethyl-2-(picolinamido)phenyl)picolinamide (H(2)Me(2)bpb) as a suitable 
      ion carrier. Poly vinylchloride (PVC)-based membrane composed of H(2)Me(2)bpb 
      with oleic acid (OA) as anionic additives, and o-nitrophenyloctyl ether (NPOE) as 
      plasticized solvent mediator. The sensor exhibits a Nernstian slope of 20.1 +/- 0.2 
      mV decade(-1) over the concentration range of 1.0 x 10(-6) to 1.0 x 1(-2) mol 
      L(-1), and a detection limit of 5.0 x 10(-7) mol L(-1) of Ho(3+) ions. The 
      potentiometric response of the sensor is independent of the solution pH in the 
      range of 3.5-9.4. It has a very short response time, in the whole concentration 
      range (<10s), and can be used for at least eight weeks. The proposed electrode 
      shows a good selectivity towards Ho(3+) ions over a wide variety of cations, 
      including alkali, alkaline earth, transition and heavy metal ions. To assess its 
      analytical applicability the proposed Ho(3+) sensor was successfully applied as 
      an indicator electrode in the titration of Ho(3+) ion solutions in certified 
      reference materials, alloy samples and for the determination of the fluoride ion 
      in two mouthwash preparations.
CI  - Copyright (c) 2012 Elsevier B.V. All rights reserved.
FAU - Zamani, Hassan Ali
AU  - Zamani HA
AD  - Department of Applied Chemistry, Mashhad Branch, Islamic Azad University, 
      Mashhad, Iran. Electronic address: haszamani@yahoo.com.
FAU - Zanganeh-Asadabadi, Abbas
AU  - Zanganeh-Asadabadi A
AD  - Department of Applied Chemistry, Quchan branch, Islamic Azad University, Quchan, 
      Iran.
FAU - Rohani, Mitra
AU  - Rohani M
AD  - Department of Applied Chemistry, Quchan branch, Islamic Azad University, Quchan, 
      Iran.
FAU - Zabihi, Mohammad Saleh
AU  - Zabihi MS
AD  - Department of Applied Chemistry, Quchan branch, Islamic Azad University, Quchan, 
      Iran.
FAU - Fadaee, Javad
AU  - Fadaee J
AD  - Department of Applied Chemistry, Quchan branch, Islamic Azad University, Quchan, 
      Iran.
FAU - Ganjali, Mohammad Reza
AU  - Ganjali MR
AD  - Center of Excellence in Electrochemistry, Faculty of Chemistry, University of 
      Tehran, Tehran, Iran.
FAU - Faridbod, Farnoush
AU  - Faridbod F
AD  - Center of Excellence in Electrochemistry, Faculty of Chemistry, University of 
      Tehran, Tehran, Iran.
FAU - Meghdadi, Soraia
AU  - Meghdadi S
AD  - Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, 
      Iran.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20121124
PL  - Netherlands
TA  - Mater Sci Eng C Mater Biol Appl
JT  - Materials science & engineering. C, Materials for biological applications
JID - 101484109
RN  - 0 (Membranes, Artificial)
RN  - 9002-86-2 (Polyvinyl Chloride)
RN  - W1XX32SQN1 (Holmium)
SB  - IM
MH  - Holmium/*analysis/chemistry
MH  - Hydrogen-Ion Concentration
MH  - *Ion-Selective Electrodes
MH  - Limit of Detection
MH  - *Membranes, Artificial
MH  - Polyvinyl Chloride/*chemistry
MH  - Potentiometry/*instrumentation/methods
MH  - Reproducibility of Results
EDAT- 2013/03/01 00:00
MHDA- 2015/07/28 06:00
CRDT- 2014/11/28 06:00
PHST- 2010/11/05 00:00 [received]
PHST- 2012/09/02 00:00 [revised]
PHST- 2012/11/17 00:00 [accepted]
PHST- 2014/11/28 06:00 [entrez]
PHST- 2013/03/01 00:00 [pubmed]
PHST- 2015/07/28 06:00 [medline]
AID - S0928-4931(12)00552-8 [pii]
AID - 10.1016/j.msec.2012.11.034 [doi]
PST - ppublish
SO  - Mater Sci Eng C Mater Biol Appl. 2013 Mar 1;33(2):984-8. doi: 
      10.1016/j.msec.2012.11.034. Epub 2012 Nov 24.