PMID- 25428036 OWN - NLM STAT- MEDLINE DCOM- 20150724 LR - 20141127 IS - 1873-0191 (Electronic) IS - 0928-4931 (Linking) VI - 33 IP - 1 DP - 2013 Jan 1 TI - Surface characteristics and electrochemical corrosion behavior of NiTi alloy coated with IrO2. PG - 15-20 LID - S0928-4931(12)00344-X [pii] LID - 10.1016/j.msec.2012.07.026 [doi] AB - The aim of this work is to investigate the surface characteristics and corrosion behavior of NiTi (50.6 at.% Ni) shape memory alloy coated by a ceramic-like and highly biocompatible material, iridium oxide (IrO2). IrO2 coatings were prepared by thermal decomposition of H2IrCl6 . 6H2O precursor solution at the temperature of 300 degrees C, 400 degrees C and 500 degrees C, respectively. The surface morphology and microstructure of the coatings were investigated by scanning electron microscope (SEM) and glancing angle X-ray diffraction (GAXRD). X-ray photoelectron spectroscopy (XPS) was employed to determine the surface elemental composition. Corrosion resistance property of the coated samples was studied in a simulated body fluid at 37+/-1 degrees C by electrochemical method. It was found that the morphology and microstructure of the coatings were closely related to the oxidizing temperatures. A relatively smooth, intact and amorphous coating was obtained when the H2IrCl6.6H2O precursor solution (0.03 mol/L) was thermally decomposed at 300 degrees C for 0.5 h. Compared with the bare NiTi alloy, IrO2 coated samples exhibited better corrosion resistance behavior to some extent. CI - Copyright (c) 2012 Elsevier B.V. All rights reserved. FAU - Li, M AU - Li M AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. FAU - Wang, Y B AU - Wang YB AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. FAU - Zhang, X AU - Zhang X AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. FAU - Li, Q H AU - Li QH AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. FAU - Liu, Q AU - Liu Q AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. FAU - Cheng, Y AU - Cheng Y AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China; Biomedical engineering research center, Shenzhen institution of Peking University, Shenzhen 518057, China. Electronic address: chengyan@pku.edu.cn. FAU - Zheng, Y F AU - Zheng YF AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China; Biomedical engineering research center, Shenzhen institution of Peking University, Shenzhen 518057, China; Department of Advanced Materials and Nanotechnology, College of Engineering, Peking University, Beijing 100871, China. FAU - Xi, T F AU - Xi TF AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China; Biomedical engineering research center, Shenzhen institution of Peking University, Shenzhen 518057, China. FAU - Wei, S C AU - Wei SC AD - Center for Biomedical Materials and Tissue Engineering, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China; Biomedical engineering research center, Shenzhen institution of Peking University, Shenzhen 518057, China; Department of Oral and Maxillofacial Surgery, School and Hospital of Stomatology, Peking University, Beijing 100871, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20120722 PL - Netherlands TA - Mater Sci Eng C Mater Biol Appl JT - Materials science & engineering. C, Materials for biological applications JID - 101484109 RN - 0 (Coated Materials, Biocompatible) RN - 12030-49-8 (iridium oxide) RN - 12035-60-8 (titanium nickelide) RN - 44448S9773 (Iridium) RN - 7OV03QG267 (Nickel) RN - D1JT611TNE (Titanium) SB - IM MH - Animals MH - Cell Death/drug effects MH - Cell Survival/drug effects MH - Coated Materials, Biocompatible/*chemistry/pharmacology MH - Corrosion MH - Electricity MH - Electrochemical Techniques/*methods MH - Electrodes MH - Fibroblasts/cytology/drug effects MH - Iridium/*chemistry MH - Mice MH - Microscopy, Electron, Scanning MH - Nickel/*chemistry/pharmacology MH - Oxidation-Reduction/drug effects MH - Photoelectron Spectroscopy MH - Surface Properties MH - Thermodynamics MH - Time Factors MH - Titanium/*chemistry/pharmacology MH - X-Ray Diffraction EDAT- 2013/01/01 00:00 MHDA- 2015/07/25 06:00 CRDT- 2014/11/28 06:00 PHST- 2012/01/27 00:00 [received] PHST- 2012/06/21 00:00 [revised] PHST- 2012/07/17 00:00 [accepted] PHST- 2014/11/28 06:00 [entrez] PHST- 2013/01/01 00:00 [pubmed] PHST- 2015/07/25 06:00 [medline] AID - S0928-4931(12)00344-X [pii] AID - 10.1016/j.msec.2012.07.026 [doi] PST - ppublish SO - Mater Sci Eng C Mater Biol Appl. 2013 Jan 1;33(1):15-20. doi: 10.1016/j.msec.2012.07.026. Epub 2012 Jul 22.