PMID- 25434122
OWN - NLM
STAT- MEDLINE
DCOM- 20150901
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 32
IP  - 8
DP  - 2014 Aug
TI  - [Simultaneous determination of cyhexatin, triphenyltin and fenbutatin oxide 
      residues in fruits and vegetables by Grignard derivatization and gas 
      chromatography coupled to tandem mass spectrometry].
PG  - 855-60
AB  - A method for the simultaneous determination of cyhexatin, triphenyltin and 
      fenbutatin oxide residues in fruits and vegetables was developed by Grignard 
      derivatization and gas chromatography coupled to tandem mass spectrometry 
      (GC-MS/MS). The samples were firstly digested by HC1/THF (1 :10, v/v), then 
      extracted by hexane and followed by the derivatization with Grignard reagent 
      (EtMgBr). Then after purification using florisil SPE columns, the sample extracts 
      were finally analyzed by GC-MS/MS. The qualitative and quantitative 
      determinations of the three organotin pesticides were performed by the tandem 
      mass in multiple reaction monitoring (MRM) mode. By using apple as a 
      representative matrix, the limits of detection (LODs) obtained by the proposed 
      method for cyhexatin, triphenyltin and fenbutatin oxide were 2. 0, 1. 5 and 3.4 
      mug/kg (as Sn), respectively. The average recoveries for the three organotin 
      pesticides were in the range of 72.4%-107. 1% at the spiked levels of 10, 20, 50 
      and 200 mug/kg (as Sn) and the relative standard deviations (RSDs) ranged from 0. 
      4% to 14. 2%. The proposed method was validated to have good linearity, high 
      sensitivity, selectivity and accuracy for the simultaneous determination of 
      cyhexatin, triphenyltin and fenbutatin oxide in fruits and vegetables. The 
      sensitivity of this method can meet the requirements of the inspection for the 
      three organotin pesticides at the level of maximum residue limits (MRLs) set by 
      China and some other countries.
FAU - Cui, Zongyan
AU  - Cui Z
FAU - Sun, Yang
AU  - Sun Y
FAU - Ge, Na
AU  - Ge N
FAU - Zhang, Jinjie
AU  - Zhang J
FAU - Liu, Yongming
AU  - Liu Y
FAU - Li, Adan
AU  - Li A
FAU - Cao, Yanzhong
AU  - Cao Y
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Organotin Compounds)
RN  - 0 (Pesticide Residues)
RN  - 0 (Trialkyltin Compounds)
RN  - 8YJV11QB4R (cyhexatin)
RN  - 95T92AGN0V (triphenyltin)
RN  - ZSV4C2L4E7 (vendex)
SB  - IM
MH  - Fruit/*chemistry
MH  - Gas Chromatography-Mass Spectrometry
MH  - Limit of Detection
MH  - Organotin Compounds/*analysis
MH  - Pesticide Residues/*analysis
MH  - Tandem Mass Spectrometry
MH  - Trialkyltin Compounds/*analysis
MH  - Vegetables/*chemistry
EDAT- 2014/12/02 06:00
MHDA- 2015/09/02 06:00
CRDT- 2014/12/02 06:00
PHST- 2014/12/02 06:00 [entrez]
PHST- 2014/12/02 06:00 [pubmed]
PHST- 2015/09/02 06:00 [medline]
AID - 10.3724/sp.j.1123.2014.04031 [doi]
PST - ppublish
SO  - Se Pu. 2014 Aug;32(8):855-60. doi: 10.3724/sp.j.1123.2014.04031.