PMID- 25446716 OWN - NLM STAT- MEDLINE DCOM- 20150226 LR - 20181202 IS - 1573-2959 (Electronic) IS - 0167-6369 (Linking) VI - 187 IP - 1 DP - 2015 Jan TI - Dissipation behavior of hexaconazole and kresoxim-methyl residues in ginseng and soil under field conditions. PG - 4126 LID - 10.1007/s10661-014-4126-6 [doi] AB - The dissipation and terminal residues of a fungicide suspension (5% hexaconazole, 25% kresoxim-methyl) in ginseng and soil were investigated by high-performance liquid chromatography coupled with tandem mass spectrometry (HPLC-MS/MS). At fortified levels of 0.01, 0.02, and 0.20 mg kg(-1), the recoveries of hexaconazole and kresoxim-methyl were in the range of 80.6 approximately 94.8% and 82.4 approximately 98.8% with relative standard deviation of 3.42-9.12% and 3.19-8.58%, respectively. The half-lives were 7.09-10.73 days in root, 6.80-7.95 days in stem, 5.31-8.49 days in leaf, and 6.30-7.97 days in soil. The terminal residues were all below the maximum residue limits (MRLs) of EU and South Korea. Risk assessment results indicated that the risk of hexaconazole and kresoxim-methyl use in ginseng at dosage of 60-90 g a.i. ha(-1) was negligible to humans. This work would help the government to establish the MRL and provide guidance on the proper and safe use of hexaconazole and kresoxim-methyl in ginseng. FAU - Wang, Yan AU - Wang Y AD - College of Agronomy, Jilin Agricultural University, Changchun, 130118, China. FAU - Liu, Chang AU - Liu C FAU - Gao, Jie AU - Gao J FAU - Wang, Chunwei AU - Wang C FAU - Cui, Lili AU - Cui L FAU - Li, Aijun AU - Li A LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20141202 PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Fungicides, Industrial) RN - 0 (Methacrylates) RN - 0 (Pesticide Residues) RN - 0 (Phenylacetates) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 0 (Strobilurins) RN - 0 (Triazoles) RN - 0LXZ062TTB (kresoxim-methyl) RN - SX9R3X1FQV (hexaconazole) SB - IM MH - Chromatography, High Pressure Liquid MH - Environmental Monitoring MH - Fungicides, Industrial/*analysis MH - Half-Life MH - Methacrylates/analysis MH - Panax/*chemistry MH - Pesticide Residues/*analysis MH - Phenylacetates/*analysis MH - Plant Leaves/chemistry MH - Plant Roots/chemistry MH - Plant Stems/chemistry MH - Republic of Korea MH - Soil/*chemistry MH - Soil Pollutants/analysis MH - Strobilurins MH - Tandem Mass Spectrometry MH - Triazoles/*analysis EDAT- 2014/12/03 06:00 MHDA- 2015/02/27 06:00 CRDT- 2014/12/03 06:00 PHST- 2014/05/20 00:00 [received] PHST- 2014/10/28 00:00 [accepted] PHST- 2014/12/03 06:00 [entrez] PHST- 2014/12/03 06:00 [pubmed] PHST- 2015/02/27 06:00 [medline] AID - 10.1007/s10661-014-4126-6 [doi] PST - ppublish SO - Environ Monit Assess. 2015 Jan;187(1):4126. doi: 10.1007/s10661-014-4126-6. Epub 2014 Dec 2.