PMID- 25454429
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20150521
LR  - 20180506
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 438
DP  - 2015 Jan 15
TI  - Fenton-like oxidation of 2,4-DCP in aqueous solution using iron-based 
      nanoparticles as the heterogeneous catalyst.
PG  - 87-93
LID - S0021-9797(14)00741-3 [pii]
LID - 10.1016/j.jcis.2014.09.082 [doi]
AB  - In this report, various iron-based nanoparticles (nZVI, n-Ni/Fe, n-Pd/Fe) were 
      used for both heterogeneous Fenton oxidation of 2,4-dichlorophenol (2,4-DCP) and 
      reductive dechlorination of 2,4-DCP in order to understand their roles in the 
      Fenton oxidation and the reductive degradation of 2,4-DCP. The dechlorination 
      efficiency of 2,4-DCP using nZVI, n-Ni/Fe, n-Fe/Pd and Fe(2)(+) was 6.48%, 6.80%, 
      15.95%, 5.02%, while Fenton oxidation efficiency of 2,4-DCP was 57.87%, 34.23%, 
      27.94%, 19.61% after 180 min, respectively. The new findings included a higher 
      dechlorination using n-Fe/Pd due to Pd effective catalysis and the effective 
      heterogeneous Fenton oxidation using nZVI depending on reductive dechlorination 
      and heterogeneous Fenton oxidation occurs simultaneously. However, nZVI as the 
      potential catalyst for heterogeneous Fenton was observed, and SEM, EDS and XRD 
      demonstrate that change on the nZVI surface occurred due to the Fe(2+) leaching, 
      and Total Organic Carbon (TOC) (30.71%) shows that 2,4-DCP was degraded. 
      Furthermore, the experiment indicates that the pH values and concentration of 
      2,4-DCP significantly impacted on the heterogeneous Fenton oxidation of 2,4-DCP 
      and the data fits well with the pseudo first-order kinetic model, which was a 
      diffusion-controlled reaction. Finally, a possible mechanism for degradation of 
      2,4-DCP was proposed.
CI  - Copyright (c) 2014 Elsevier Inc. All rights reserved.
FAU - Li, Renchao
AU  - Li R
AD  - School of Environment Science and Engineering, Fujian Normal University, Fuzhou 
      350007, Fujian Province, China.
FAU - Gao, Ying
AU  - Gao Y
AD  - School of Environment Science and Engineering, Fujian Normal University, Fuzhou 
      350007, Fujian Province, China.
FAU - Jin, Xiaoying
AU  - Jin X
AD  - School of Environment Science and Engineering, Fujian Normal University, Fuzhou 
      350007, Fujian Province, China.
FAU - Chen, Zuliang
AU  - Chen Z
AD  - School of Environment Science and Engineering, Fujian Normal University, Fuzhou 
      350007, Fujian Province, China; Centre for Environmental Risk Assessment and 
      Remediation, University of South Australia, Mawson Lakes, SA 5095, Australia; 
      Cooperative Research Centre for Contamination Assessment and Remediation of 
      Environments, Mawson Lakes, SA 5095, Australia. Electronic address: 
      Zuliang.chen@unisa.edu.au.
FAU - Megharaj, Mallavarapu
AU  - Megharaj M
AD  - Centre for Environmental Risk Assessment and Remediation, University of South 
      Australia, Mawson Lakes, SA 5095, Australia; Cooperative Research Centre for 
      Contamination Assessment and Remediation of Environments, Mawson Lakes, SA 5095, 
      Australia.
FAU - Naidu, Ravendra
AU  - Naidu R
AD  - Centre for Environmental Risk Assessment and Remediation, University of South 
      Australia, Mawson Lakes, SA 5095, Australia; Cooperative Research Centre for 
      Contamination Assessment and Remediation of Environments, Mawson Lakes, SA 5095, 
      Australia.
LA  - eng
PT  - Journal Article
DEP - 20141013
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
OTO - NOTNLM
OT  - 2,4-DCP
OT  - Heterogeneous Fenton oxidation
OT  - Nanocatalyst
OT  - nZVI
EDAT- 2014/12/03 06:00
MHDA- 2014/12/03 06:01
CRDT- 2014/12/03 06:00
PHST- 2014/06/11 00:00 [received]
PHST- 2014/09/27 00:00 [revised]
PHST- 2014/09/30 00:00 [accepted]
PHST- 2014/12/03 06:00 [entrez]
PHST- 2014/12/03 06:00 [pubmed]
PHST- 2014/12/03 06:01 [medline]
AID - S0021-9797(14)00741-3 [pii]
AID - 10.1016/j.jcis.2014.09.082 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2015 Jan 15;438:87-93. doi: 10.1016/j.jcis.2014.09.082. 
      Epub 2014 Oct 13.